Structured catalysts and catalytic processes: transport and reaction perspectives

C Pei, S Chen, D Fu, ZJ Zhao, J Gong - Chemical Reviews, 2024 - ACS Publications
The structure of catalysts determines the performance of catalytic processes. Intrinsically, the
electronic and geometric structures influence the interaction between active species and the …

Chemical loo**-based energy transformation via lattice oxygen modulated selective oxidation

Z Sun, CK Russell, KJ Whitty, EG Eddings, J Dai… - Progress in Energy and …, 2023 - Elsevier
Modulating anionic oxygen in metal oxides offers exceptional opportunities for energy
material synthesis via redox loo**; however, several challenges such as overoxidation …

Defective TiOx overlayers catalyze propane dehydrogenation promoted by base metals

S Chen, Y Xu, X Chang, Y Pan, G Sun, X Wang, D Fu… - Science, 2024 - science.org
The industrial catalysts utilized for propane dehydrogenation (PDH) to propylene, an
important alternative to petroleum-based cracking processes, either use expensive metals or …

Propane dehydrogenation: catalyst development, new chemistry, and emerging technologies

S Chen, X Chang, G Sun, T Zhang, Y Xu… - Chemical SOCIETY …, 2021 - pubs.rsc.org
Propylene is an important building block for enormous petrochemicals including
polypropylene, propylene oxide, acrylonitrile and so forth. Propane dehydrogenation (PDH) …

Light olefin synthesis from a diversity of renewable and fossil feedstocks: state-of the-art and outlook

SA Chernyak, M Corda, JP Dath… - Chemical Society …, 2022 - pubs.rsc.org
Light olefins are important feedstocks and platform molecules for the chemical industry.
Their synthesis has been a research priority in both academia and industry. There are many …

Recent progress in heterogeneous metal and metal oxide catalysts for direct dehydrogenation of ethane and propane

Y Dai, X Gao, Q Wang, X Wan, C Zhou… - Chemical Society …, 2021 - pubs.rsc.org
Catalytic non-oxidative direct dehydrogenation of light alkanes serves as an effective
reinforcement to selectively produce the corresponding olefins, and the heterogeneous …

Subsurface A-site vacancy activates lattice oxygen in perovskite ferrites for methane anaerobic oxidation to syngas

J He, T Wang, X Bi, Y Tian, C Huang, W Xu… - Nature …, 2024 - nature.com
Tuning the oxygen activity in perovskite oxides (ABO3) is promising to surmount the trade-off
between activity and selectivity in redox reactions. However, this remains challenging due to …

Tandem propane dehydrogenation and surface oxidation catalysts for selective propylene synthesis

W Wang, S Chen, C Pei, R Luo, J Sun, H Song, G Sun… - Science, 2023 - science.org
Direct propane dehydrogenation (PDH) to propylene is a desirable commercial reaction but
is highly endothermic and severely limited by thermodynamic equilibrium. Routes that …

Tandem In2O3-Pt/Al2O3 catalyst for coupling of propane dehydrogenation to selective H2 combustion

H Yan, K He, IA Samek, D **g, MG Nanda, PC Stair… - Science, 2021 - science.org
Tandem catalysis couples multiple reactions and promises to improve chemical processing,
but precise spatiotemporal control over reactive intermediates remains elusive. We used …

Isolated boron in zeolite for oxidative dehydrogenation of propane

H Zhou, X Yi, Y Hui, L Wang, W Chen, Y Qin, M Wang… - Science, 2021 - science.org
Oxidative dehydrogenation of propane (ODHP) is a key technology for producing propene
from shale gas, but conventional metal oxide catalysts are prone to overoxidation to form …