The use of light to mediate controlled radical polymerization has emerged as a powerful
strategy for rational polymer synthesis and advanced materials fabrication. This review …

Block copolymers form the basis of the most ubiquitous materials such as thermoplastic
elastomers, bridge interphases in polymer blends, and are fundamental for the development …

Photomediated controlled radical polymerization is a versatile method to prepare, under
mild conditions, various well-defined polymers with complex architecture, such as block and …

Reversible-deactivation radical polymerisation (RDRP) techniques are essential in modern
polymer chemistry. Over the years, they have become not only fantastic lab tools for the easy …

Organocobalt (III) complexes (R-CoIII), defined as cobalt complexes featuring a carbon–
cobalt bond, are largely used to produce carbon-centered radicals by homolytic cleavage of …

Porphyrins and their derivatives have attracted great attention due to their unique properties
and diverse functionalities which contribute to their wide applications such as catalysis, solar …

Molecularly imprinted polymers (MIPs) are promising receptors for a wide range of targeted
molecules. In recent years, the construction of low molecular weight materials became …

Polycarbazole and its derivatives have been extensively used for the last three decades,
although the interest in these materials briefly decreased. However, the increasing demand …

A growing and useful class of alkene coupling reactions involve hydrogen atom transfer
(HAT) from a metal-hydride species to an alkene to form a free radical, which is responsible …

A short review of the role of photocatalysts in photopolymerization reactions is presented. A
special emphasis is placed on photoredox catalysts leading to i) high‐performance initiating …