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Single ion magnets from 3d to 5f: developments and strategies
M Feng, ML Tong - Chemistry–A European Journal, 2018 - Wiley Online Library
Abstract Single‐ion magnets (SIMs), exhibiting slow magnetization relaxation in the absence
of the magnetic field, originate from their single spin‐carrier centre. In pursuit of high …
of the magnetic field, originate from their single spin‐carrier centre. In pursuit of high …
Magnetic anisotropy of transition metal and lanthanide ions in pentagonal bipyramidal geometry
The magnetic anisotropy associated with a pentagonal bipyramidal (PBP) coordination
sphere is examined on the basis of experimental and theoretical investigations. The origin …
sphere is examined on the basis of experimental and theoretical investigations. The origin …
A dysprosium metallocene single‐molecule magnet functioning at the axial limit
Abstraction of a chloride ligand from the dysprosium metallocene [(Cpttt) 2DyCl](1Dy Cpttt=
1, 2, 4‐tri (tert‐butyl) cyclopentadienide) by the triethylsilylium cation produces the first base …
1, 2, 4‐tri (tert‐butyl) cyclopentadienide) by the triethylsilylium cation produces the first base …
Emerging trends on designing high-performance dysprosium (III) single-molecule magnets
TG Ashebr, H Li, X Ying, XL Li, C Zhao, S Liu… - ACS Materials …, 2022 - ACS Publications
The present prospect of single-molecule magnets (SMMs) research is more appealing after
the detection of magnetic remanence above liquid-nitrogen temperatures. From the current …
the detection of magnetic remanence above liquid-nitrogen temperatures. From the current …
Insight into D6h Symmetry: Targeting Strong Axiality in Stable Dysprosium(III) Hexagonal Bipyramidal Single‐Ion Magnets
AB Canaj, S Dey, ER Martí, C Wilson… - Angewandte Chemie …, 2019 - Wiley Online Library
Following a novel synthetic strategy where the strong uniaxial ligand field generated by the
Ph3SiO−(Ph3SiO−= anion of triphenylsilanol) and the 2, 4‐di‐tBu‐PhO−(2, 4‐di‐tBu‐PhO …
Ph3SiO−(Ph3SiO−= anion of triphenylsilanol) and the 2, 4‐di‐tBu‐PhO−(2, 4‐di‐tBu‐PhO …
Ab initio prediction of high-temperature magnetic relaxation rates in single-molecule magnets
Organometallic molecules based on [Dy (CpR) 2]+ cations (where CpR is a substituted
cyclopentadienyl anion) have emerged as clear front-runners in the search for high …
cyclopentadienyl anion) have emerged as clear front-runners in the search for high …
A Study of Magnetic Relaxation in Dysprosium (III) Single‐Molecule Magnets
YS Ding, T Han, YQ Zhai, D Reta… - … A European Journal, 2020 - Wiley Online Library
Although the development of single‐molecule magnets (SMMs) is rapid, there are only two
families of high energy barrier (Ueff) dysprosium (III) SMMs known so far: the …
families of high energy barrier (Ueff) dysprosium (III) SMMs known so far: the …
Proton Conductive Luminescent Thermometer Based on Near-Infrared Emissive {YbCo2} Molecular Nanomagnets
Lanthanide (III)-based coordination complexes have been explored as a source of
bifunctional molecular materials combining Single-Molecule Magnet (SMM) behavior with …
bifunctional molecular materials combining Single-Molecule Magnet (SMM) behavior with …
Radical‐Bridged Ln4 Metallocene Complexes with Strong Magnetic Coupling and a Large Coercive Field
Inducing magnetic coupling between 4f elements is an ongoing challenge. To overcome this
formidable difficulty, we incorporate highly delocalized tetrazinyl radicals, which strongly …
formidable difficulty, we incorporate highly delocalized tetrazinyl radicals, which strongly …
High performance single-molecule magnets, Orbach or Raman relaxation suppression?
The current figure of merit to evaluate Single Molecule Magnet (SMM) performance is the
blocking temperature (TB). The best SMMs show TB values close to liquid nitrogen boiling …
blocking temperature (TB). The best SMMs show TB values close to liquid nitrogen boiling …