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Manganese-catalyzed hydrogenation, dehydrogenation, and hydroelementation reactions
The emerging field of organometallic catalysis has shifted towards research on Earth-
abundant transition metals due to their ready availability, economic advantage, and novel …
abundant transition metals due to their ready availability, economic advantage, and novel …
Borrowing hydrogen for organic synthesis
BG Reed-Berendt, DE Latham, MB Dambatta… - ACS central …, 2021 - ACS Publications
Borrowing hydrogen is a process that is used to diversify the synthetic utility of commodity
alcohols. A catalyst first oxidizes an alcohol by removing hydrogen to form a reactive …
alcohols. A catalyst first oxidizes an alcohol by removing hydrogen to form a reactive …
Alcohols as substrates in transition-metal-catalyzed arylation, alkylation, and related reactions
Alcohols are abundant and attractive feedstock molecules for organic synthesis. Many
methods for their functionalization require them to first be converted into a more activated …
methods for their functionalization require them to first be converted into a more activated …
3d-Metal catalyzed N-and C-alkylation reactions via borrowing hydrogen or hydrogen autotransfer
The conservation of our element resources is a fundamental challenge of mankind. The
development of alcohol refunctionalization reactions is a possible fossil carbon conservation …
development of alcohol refunctionalization reactions is a possible fossil carbon conservation …
Homogeneous manganese-catalyzed hydrogenation and dehydrogenation reactions
Y Wang, M Wang, Y Li, Q Liu - Chem, 2021 - cell.com
The development of novel and efficient earth-abundant metal catalysts as inexpensive and
sustainable alternatives to noble-metal catalysts is a rapidly expanding and evolving field of …
sustainable alternatives to noble-metal catalysts is a rapidly expanding and evolving field of …
Enable biomass-derived alcohols mediated alkylation and transfer hydrogenation
X Liu, L Huang, Y Ma, G She, P Zhou, L Zhu… - Nature …, 2024 - nature.com
A single-atom catalyst with generally regarded inert Zn–N4 motifs derived from ZIF-8 is
unexpectedly efficient for the activation of alcohols, enabling alcohol-mediated alkylation …
unexpectedly efficient for the activation of alcohols, enabling alcohol-mediated alkylation …
Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes
Rapidly emerging application of organometallic manganese complexes incorporating less
elaborated mono-and bidentate donor ligands in catalytic hydrogenation, transfer …
elaborated mono-and bidentate donor ligands in catalytic hydrogenation, transfer …
Sustainable synthesis of quinazoline and 2-aminoquinoline via dehydrogenative coupling of 2-aminobenzyl alcohol and nitrile catalyzed by phosphine-free …
A sustainable synthesis of quinazoline and 2-aminoquinoline via acceptorless
dehydrogenative annulation is presented. The reaction is catalyzed by earth-abundant well …
dehydrogenative annulation is presented. The reaction is catalyzed by earth-abundant well …
Recent advancement in oxidation or acceptorless dehydrogenation of alcohols to valorised products using manganese based catalysts
Manganese based compounds have gained much interest as catalytic materials due to their
natural abundance, biocompatibility, and multiple oxidation states. Manganese-based …
natural abundance, biocompatibility, and multiple oxidation states. Manganese-based …
Catalytic C1 Alkylation with Methanol and Isotope‐Labeled Methanol
A metal‐catalyzed methylation process has been developed. By employing an air‐and
moisture‐stable manganese catalyst together with isotopically labeled methanol, a series of …
moisture‐stable manganese catalyst together with isotopically labeled methanol, a series of …