Atomically precise alloy nanoclusters: syntheses, structures, and properties

X Kang, Y Li, M Zhu, R ** - Chemical Society Reviews, 2020 - pubs.rsc.org
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles,
providing unique opportunities for investigating the quantum effects and precise structure …

Au 25 (SR) 18: the captain of the great nanocluster ship

X Kang, H Chong, M Zhu - Nanoscale, 2018 - pubs.rsc.org
Noble metal nanoclusters are in the intermediate state between discrete atoms and
plasmonic nanoparticles and are of significance due to their atomically accurate structures …

Alloy clusters: precise synthesis and mixing effects

S Hossain, Y Niihori, LV Nair, B Kumar… - Accounts of Chemical …, 2018 - ACS Publications
Conspectus Metal alloys exhibit functionalities unlike those of single metals. Such alloying
has drawn considerable research interest, particularly for nanoscale particles (metal …

Reactivity of metal clusters

Z Luo, AW Castleman Jr, SN Khanna - Chemical reviews, 2016 - ACS Publications
We summarize here the research advances on the reactivity of metal clusters. After a simple
introduction of apparatuses used for gas-phase cluster reactions, we focus on the reactivity …

Electronic and geometric structure, optical properties, and excited state behavior in atomically precise thiolate-stabilized noble metal nanoclusters

CM Aikens - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus Ligand-protected noble metal nanoclusters are of interest for their potential
applications in areas such as bioimaging, catalysis, photocatalysis, and solar energy …

Quantum mechanical studies of large metal, metal oxide, and metal chalcogenide nanoparticles and clusters

A Fernando, KLDM Weerawardene… - Chemical …, 2015 - ACS Publications
Metal, metal oxide, and metal chalcogenide materials have a wide variety of applications.
For example, many metal clusters and nanoparticles are used as catalysts for reactions …

Customizing the structure, composition, and properties of alloy nanoclusters by metal exchange

S Wang, Q Li, X Kang, M Zhu - Accounts of chemical research, 2018 - ACS Publications
Conspectus The properties of metal materials can be greatly enriched by including various
elements to generate alloys. The galvanic replacement represents a classical method for the …

Monoplatinum do** of gold nanoclusters and catalytic application

H Qian, D Jiang, G Li, C Gayathri, A Das… - Journal of the …, 2012 - ACS Publications
We report single-atom do** of gold nanoclusters (NCs), and its drastic effects on the
optical, electronic, and catalytic properties, using the 25-atom system as a model. In our …

Precise synthesis, functionalization and application of thiolate-protected gold clusters

W Kurashige, Y Niihori, S Sharma, Y Negishi - Coordination Chemistry …, 2016 - Elsevier
Thiolate-protected gold clusters (Au n (SR) m) have received significant attention as new
functional nanomaterials because they exhibit size-specific physical and chemical …

Metal Exchange Method Using Au25 Nanoclusters as Templates for Alloy Nanoclusters with Atomic Precision

S Wang, Y Song, S **, X Liu, J Zhang… - Journal of the …, 2015 - ACS Publications
A metal exchange method based upon atomically precise gold nanoclusters (NCs) as
templates is devised to obtain alloy NCs including Cu x Au25-x (SR) 18, Ag x Au25-x (SR) …