Non-adiabatic excited-state molecular dynamics: Theory and applications for modeling photophysics in extended molecular materials

TR Nelson, AJ White, JA Bjorgaard, AE Sifain… - Chemical …, 2020 - ACS Publications
Optically active molecular materials, such as organic conjugated polymers and biological
systems, are characterized by strong coupling between electronic and vibrational degrees of …

Polarizable continuum model

B Mennucci - Wiley Interdisciplinary Reviews: Computational …, 2012 - Wiley Online Library
The polarizable continuum model (PCM) is a computational method originally formulated 30
years ago but still today it represents one of the most successful examples among …

[HTML][HTML] Octopus, a computational framework for exploring light-driven phenomena and quantum dynamics in extended and finite systems

N Tancogne-Dejean, MJT Oliveira… - The Journal of …, 2020 - pubs.aip.org
Over the last few years, extraordinary advances in experimental and theoretical tools have
allowed us to monitor and control matter at short time and atomic scales with a high degree …

Quantum mechanical studies on the photophysics and the photochemistry of nucleic acids and nucleobases

R Improta, F Santoro, L Blancafort - Chemical reviews, 2016 - ACS Publications
The photophysics and photochemistry of DNA is of great importance due to the potential
damage of the genetic code by UV light. Quantum mechanical studies have played a key …

Dielectric continuum methods for quantum chemistry

JM Herbert - Wiley Interdisciplinary Reviews: Computational …, 2021 - Wiley Online Library
This review describes the theory and implementation of implicit solvation models based on
continuum electrostatics. Within quantum chemistry this formalism is sometimes …

A state-specific polarizable continuum model time dependent density functional theory method for excited state calculations in solution

R Improta, V Barone, G Scalmani… - The Journal of chemical …, 2006 - pubs.aip.org
An effective state specific (SS) model for the inclusion of solvent effects in time dependent
density functional theory (TD-DFT) computations of excited electronic states has been …

Polarizable embedding QM/MM: the future gold standard for complex (bio) systems?

M Bondanza, M Nottoli, L Cupellini… - Physical Chemistry …, 2020 - pubs.rsc.org
Nowadays, hybrid QM/MM approaches are widely used to study (supra) molecular systems
embedded in complex biological matrices. However, in their common formulation, mutual …

Formation and relaxation of excited states in solution: A new time dependent polarizable continuum model based on time dependent density functional theory

M Caricato, B Mennucci, J Tomasi, F Ingrosso… - The Journal of …, 2006 - pubs.aip.org
In this paper a novel approach to study the formation and relaxation of excited states in
solution is presented within the integral equation formalism version of the polarizable …

Toward effective and reliable fluorescence energies in solution by a new state specific polarizable continuum model time dependent density functional theory …

R Improta, G Scalmani, MJ Frisch… - The Journal of chemical …, 2007 - pubs.aip.org
A state specific (SS) model for the inclusion of solvent effects in time dependent density
functional theory (TD-DFT) computations of emission energies has been developed and …

Excited-state calculations with TD-DFT: from benchmarks to simulations in complex environments

D Jacquemin, B Mennucci, C Adamo - Physical chemistry chemical …, 2011 - pubs.rsc.org
In this perspective, we present an overview of recent progress on Time-Dependent Density
Functional Theory (TD-DFT) with a specific focus on its accuracy and on models able to take …