We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …

Conspectus Oxidative cross-coupling has proved to be one of the most straightforward
strategies for forming carbon–carbon and carbon–heteroatom bonds from easily available …

Conspectus To improve the efficacy of molecular syntheses, researchers wish to capitalize
upon the selective modification of otherwise inert C–H bonds. The past two decades have …

Oxidative C–H/N–H cross-coupling has emerged as an atom-economical method for the
construction of C–N bonds. Conventional oxidative C–H/N–H coupling requires at least one …

Photo-/electrochemical catalyzed oxidative R1-H/R2-H cross-coupling with hydrogen
evolution has become an increasingly important issue for molecular synthesis. The dream of …

Electrochemical transition metal catalysis is a powerful strategy for organic synthesis
because it obviates the use of stoichiometric chemical oxidants and reductants. C–H bond …

Carbon dioxide (CO2) is an abundant, inexpensive, renewable C1 resource and the main
component of greenhouse gas, thereby the research for its sustainable and efficient …

Oxidative R1–H/R2–H cross-coupling with hydrogen evolution serves as one of the most
atom-economical methods for constructing new chemical bonds. This reaction strategy …

Phenols and their derivatives are the elementary building blocks for several classes of
complex molecules that play essential roles in biological systems. Nature has devised …

An efficient electrochemical approach for the C (sp2)–H phosphonation of quinoxalin-2 (1H)-
ones and C (sp3)–H phosphonation of xanthenes has been developed. The chemistry was …