Oxide–and silicate–water interfaces and their roles in technology and the environment

JL Bañuelos, E Borguet, GE Brown Jr… - Chemical …, 2023 - ACS Publications
Interfacial reactions drive all elemental cycling on Earth and play pivotal roles in human
activities such as agriculture, water purification, energy production and storage …

[HTML][HTML] The pH dependent surface charging and points of zero charge. VIII. Update

M Kosmulski - Advances in Colloid and Interface Science, 2020 - Elsevier
A critical review of the points of zero charge (PZC) obtained by potentiometric titration and of
isoelectric points (IEP) obtained by electrokinetic measurements. The results from the recent …

Probing the mineral–water interface with nonlinear optical spectroscopy

EHG Backus, J Schaefer, M Bonn - … Chemie International Edition, 2021 - Wiley Online Library
The interaction between minerals and water is manifold and complex: the mineral surface
can be (de) protonated by water, thereby changing its charge; mineral ions dissolved into …

Vibrational spectroscopy of geochemical interfaces

SM Piontek, E Borguet - Surface Science Reports, 2023 - Elsevier
Mineral/aqueous interfaces are ubiquitous in geochemistry and are employed for
applications spanning catalysis to CO 2 sequestration. Small changes in interface …

Quantifying double-layer potentials at liquid–gas interfaces from vibrational sum-frequency generation

N García Rey, E Weißenborn… - The Journal of …, 2018 - ACS Publications
Vibrational sum-frequency generation (SFG) spectroscopy is demonstrated as a fast method
to quantify variations of the electric double-layer potential ϕ0 at liquid–gas interfaces. For …

Vibrational dynamics at aqueous–mineral interfaces

SM Piontek, E Borguet - The Journal of Physical Chemistry C, 2022 - ACS Publications
The dynamics of water at mineral surfaces has attracted much attention due to the marked
differences, compared to the bulk, in the ability of interfacial water populations to redistribute …

Structure and Reactivity of α-Al2O3(0001) Surfaces: How Do Al–I and Gibbsite-like Terminations Interconvert?

Y Yue, G Melani, H Kirsch, A Paarmann… - The Journal of …, 2022 - ACS Publications
The α-Al2O3 (0001) surface has been extensively studied because of its significance in both
fundamental research and application. Prior work suggests that in ultra-high-vacuum (UHV) …

Probing Heterogeneous Charge Distributions at the α-Al2O3(0001)/H2O Interface

SM Piontek, M DelloStritto, B Mandal… - Journal of the …, 2020 - ACS Publications
Unlike metal or semiconductor electrodes, the surface charge resulting from the protonation
or deprotonation of insulating mineral oxides is highly localized and heterogeneous in …

Acidity constants of the hematite–liquid water interface from ab initio molecular dynamics

OR Gittus, GF Von Rudorff, KM Rosso… - The journal of physical …, 2018 - ACS Publications
The interface between transition metal oxides (TMO) and liquid water plays a crucial role in
environmental chemistry, catalysis, and energy science. Yet, the mechanism and energetics …

[HTML][HTML] Investigations on the properties and performance of mixed-matrix polyethersulfone membranes modified with halloysite nanotubes

S Mozia, A Grylewicz, M Zgrzebnicki, D Darowna… - Polymers, 2019 - mdpi.com
Ultrafiltration (UF) polyethersulfone (PES) membranes were prepared by wet phase
inversion method. Commercial halloysite nanotubes (HNTs) in the amount of 0.5–4 wt% vs …