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Step-growth polymerization by the RAFT process
Reversible Addition-Fragmentation Chain Transfer (RAFT) step-growth polymerization is an
emerging method that synergistically combines the benefits of RAFT polymerization …
emerging method that synergistically combines the benefits of RAFT polymerization …
[HTML][HTML] Radical-promoted single-unit monomer insertion (SUMI)[aka. reversible-deactivation radical addition (RDRA)]
We survey progress in the development of the processes for radical-promoted single-unit
monomer insertion (SUMI) or reversible deactivation radical addition (RDRA), focussing on …
monomer insertion (SUMI) or reversible deactivation radical addition (RDRA), focussing on …
Controlled switching thiocarbonylthio end-groups enables interconvertible radical and cationic single-unit monomer insertions and RAFT polymerizations
W He, W Tao, Z Wei, G Tong, X Liu, J Tan… - Nature …, 2024 - nature.com
To emulate the ordered arrangement of monomer units found in natural macromolecules,
single-unit monomer insertion (SUMI) have emerged as a potent technique for synthesizing …
single-unit monomer insertion (SUMI) have emerged as a potent technique for synthesizing …
Unique polymer-stabilized liquid crystal structure prepared by addition of a reversible addition–fragmentation chain transfer agent
Y Zhang, Q Zhan, C Wang, J Gao, G Zhou… - … Applied Materials & …, 2023 - ACS Publications
Polymer-stabilized liquid crystals (PSLCs) are important electrically switchable materials
due to their superior electro-optical properties. Nevertheless, it remains a formidable …
due to their superior electro-optical properties. Nevertheless, it remains a formidable …
Tuning the Mechanical Properties of 3D‐printed Objects by the RAFT Process: From Chain‐Growth to Step‐Growth
Photoinduced 3D printing based on the reversible addition‐fragmentation chain transfer
(RAFT) process has emerged as a robust method for creating diverse functional materials …
(RAFT) process has emerged as a robust method for creating diverse functional materials …
RAFT step-growth polymerization of bis-acrylamides and their facile degradation
Demonstrated is the successful A2+ B2 RAFT step-growth polymerization of bis-acrylamides
using a bifunctional trithiocarbonate chain transfer agent as the comonomer. Remarkably …
using a bifunctional trithiocarbonate chain transfer agent as the comonomer. Remarkably …
Preparation of fluorinated polyesters by reversible addition–fragmentation chain transfer step-growth polymerization
Fluorinated polyesters have demonstrated significant research value and application
prospects, while their traditional synthetic strategies were restrained by harsh reaction …
prospects, while their traditional synthetic strategies were restrained by harsh reaction …
Step-growth irreversible deactivation radical polymerization: synergistic developments with chain-growth reversible deactivation radical polymerization
Recent advances in chain-growth reversible deactivation radical polymerization (CG-
RDRP), ie the so-called “living radical polymerization”, have synergistically developed step …
RDRP), ie the so-called “living radical polymerization”, have synergistically developed step …
Orthogonal Radical and Cationic Single‐Unit Monomer Insertions for Engineering Polymer Architectures
Z Wei, W He, Z Liu, Y Lin, M Wang, L Li… - Angewandte …, 2024 - Wiley Online Library
The single‐unit monomer insertion (SUMI), derived from living/controlled polymerization,
can be directly functionalized at the end or within the chain of polymers prepared by …
can be directly functionalized at the end or within the chain of polymers prepared by …
Geometric confinement growth of wax crystals by star acrylate polymer for enhanced cold flowability of waxy crudes
X Sun, L Jia, X Li, S Zhang, Y Wang, M Fan, J Xu - Fuel, 2024 - Elsevier
Wax precipitation causes numerous challenges in the transportation and refining of crude
oil. Wax deposition can be decreased and the flowability of waxy crude oil in cold …
oil. Wax deposition can be decreased and the flowability of waxy crude oil in cold …