Organosulfur compounds have long played a vital role in organic chemistry and in the
development of novel chemical structures and architectures. Prominent among these …

Conspectus Over recent decades, N-sulfonylhydrazones have attracted significant attention
in academic and industrial contexts owing to their ease of preparation, versatile reactivity …

Asymmetric sigmatropic rearrangement is a powerful organic transformation via substrate-
reorganization to efficiently increase molecular complexity from readily accessible starting …

Abstract [2, 3]‐Sigmatropic rearrangement reaction involving sulfonium ylide (Doyle–Kirmse
reaction) generated from metal carbenes represents one of the powerful methods for the …

Here, we report a copper‐catalyzed asymmetric cascade cyclization/[1, 2]‐Stevens‐type
rearrangement via a non‐diazo approach, leading to the practical and atom‐economic …

Among the available methods to increase the molecular complexity, sigmatropic
rearrangements occupy a distinct position in organic synthesis. Despite being known for …

This Feature Article is aimed at highlighting the recent developments in the transition-metal-
free molecular rearrangements involving arynes. The chemistry of arynes has shown …

The trifluoromethylthio (SCF3) functional group has been of increasing importance in drug
design and development as a consequence of its unique electronic properties and high …

A first example of low-energy blue-light-mediated formal Doyle–Kirmse reaction for gem-
difluoroallylation of aryl diazoesters has been developed. A variety of highly functionalized …

In this study, we present a novel and efficient approach for the oxidative esterification of
sulfenamides using phenyliodonium diacetate, enabling the synthesis of sulfinimidate esters …