Variational transition state theory: theoretical framework and recent developments

JL Bao, DG Truhlar - Chemical Society Reviews, 2017 - pubs.rsc.org
This article reviews the fundamentals of variational transition state theory (VTST), its recent
theoretical development, and some modern applications. The theoretical methods reviewed …

Multiconfiguration self-consistent field and multireference configuration interaction methods and applications

PG Szalay, T Muller, G Gidofalvi, H Lischka… - Chemical …, 2012 - ACS Publications
The configuration interaction (CI) method is a general procedure to compute approximate
solutions to the electronic Schrödinger equation. The wave function is written as a linear …

Numerical simulation of lean premixed combustion characteristics and emissions of natural gas-ammonia dual-fuel marine engine with the pre-chamber ignition …

X Wu, Y Feng, Y Gao, C **a, Y Zhu, M Shreka, P Ming - Fuel, 2023 - Elsevier
As an efficient hydrogen carrier, ammonia (NH 3) has great potential to realize the target of
carbon neutralization. In this paper, a natural gas-ammonia dual-fuel engine model has …

A Hierarchical and Comparative Kinetic Modeling Study of C1 − C2 Hydrocarbon and Oxygenated Fuels

WK Metcalfe, SM Burke, SS Ahmed… - International Journal of …, 2013 - Wiley Online Library
ABSTRACT A detailed chemical kinetic mechanism has been developed to describe the
oxidation of small hydrocarbon and oxygenated hydrocarbon species. The reactivity of these …

Comprehensive H2/O2 kinetic model for high‐pressure combustion

MP Burke, M Chaos, Y Ju, FL Dryer… - … Journal of Chemical …, 2012 - Wiley Online Library
An updated H2/O2 kinetic model based on that of Li et al.(Int J Chem Kinet 36, 2004, 566–
575) is presented and tested against a wide range of combustion targets. The primary …

From theoretical reaction dynamics to chemical modeling of combustion

SJ Klippenstein - Proceedings of the Combustion Institute, 2017 - Elsevier
The chemical modeling of combustion treats the chemical conversion of hundreds of species
through thousands of reactions. Recent advances in theoretical methodologies and …

Simulating the density of organic species in the atmosphere of Titan with a coupled ion-neutral photochemical model

V Vuitton, RV Yelle, SJ Klippenstein, SM Hörst… - Icarus, 2019 - Elsevier
We present a one-dimensional coupled ion-neutral photochemical kinetics and diffusion
model to study the atmospheric composition of Titan in light of new theoretical kinetics …

Kinetics of elementary reactions in low-temperature autoignition chemistry

J Zádor, CA Taatjes, RX Fernandes - Progress in energy and combustion …, 2011 - Elsevier
Advanced low-temperature combustion concepts that rely on compression ignition have
placed new technological demands on the modeling of low-temperature oxidation in general …

The role of NNH in NO formation and control

SJ Klippenstein, LB Harding, P Glarborg… - Combustion and Flame, 2011 - Elsevier
One of the remaining issues in our understanding of nitrogen chemistry in combustion is the
chemistry of NNH. This species is known as a key intermediate in Thermal DeNOx, where …

Modeling the kinetics of bimolecular reactions

A Fernández-Ramos, JA Miller, SJ Klippenstein… - Chemical …, 2006 - ACS Publications
This review is concerned with the theoretical and computational modeling of bimolecular
reactions, especially with generally applicable methods for kinetics (ie, overall rates as …