A comparison of RAFT and ATRP methods for controlled radical polymerization
Reversible addition–fragmentation chain-transfer (RAFT) polymerization and atom transfer
radical polymerization (ATRP) are the two most common controlled radical polymerization …
radical polymerization (ATRP) are the two most common controlled radical polymerization …
Linear block copolymer synthesis
Block copolymers form the basis of the most ubiquitous materials such as thermoplastic
elastomers, bridge interphases in polymer blends, and are fundamental for the development …
elastomers, bridge interphases in polymer blends, and are fundamental for the development …
Seeing the light: advancing materials chemistry through photopolymerization
The application of photochemistry to polymer and material science has led to the
development of complex yet efficient systems for polymerization, polymer post …
development of complex yet efficient systems for polymerization, polymer post …
Photoinduced controlled/living polymerizations
The application of photochemistry in polymer synthesis is of interest due to the unique
possibilities offered compared to thermochemistry, including topological and temporal …
possibilities offered compared to thermochemistry, including topological and temporal …
Olefins and vinyl polar monomers: bridging the gap for next generation materials
The inherent differences in reactivity between activated and non‐activated alkenes prevents
copolymerization using established polymer synthesis techniques. Research over the past …
copolymerization using established polymer synthesis techniques. Research over the past …
A Counterion/Ligand-Tuned Chemo-and Enantioselective Copper-Catalyzed Intermolecular Radical 1, 2-Carboamination of Alkenes
XY Cheng, YF Zhang, JH Wang, QS Gu… - Journal of the …, 2022 - ACS Publications
The copper-catalyzed enantioselective intermolecular radical 1, 2-carboamination of
alkenes with readily accessible alkyl halides is an appealing strategy for producing chiral …
alkenes with readily accessible alkyl halides is an appealing strategy for producing chiral …
Fully oxygen-tolerant visible-light-induced ATRP of acrylates in water: toward synthesis of protein-polymer hybrids
Over the last decade, photoinduced ATRP techniques have been developed to harness the
energy of light to generate radicals. Most of these methods require the use of UV light to …
energy of light to generate radicals. Most of these methods require the use of UV light to …
Cereblon covalent modulation through structure-based design of histidine targeting chemical probes
Electrophilic biocompatible warheads, particularly cysteine-reactive acrylamides, have
enabled the development of covalent inhibitor drugs and chemical biology probes, but …
enabled the development of covalent inhibitor drugs and chemical biology probes, but …
Biocatalytic “Oxygen‐Fueled” Atom Transfer Radical Polymerization
Atom transfer radical polymerization (ATRP) can be carried out in a flask completely open to
air using a biocatalytic system composed of glucose oxidase (GOx) and horseradish …
air using a biocatalytic system composed of glucose oxidase (GOx) and horseradish …
1, 8-Naphthalimide-based polymers exhibiting deep-red thermally activated delayed fluorescence and their application in ratiometric temperature sensing
A series of naphthalimide (NAI)-based red-emissive thermally activated delayed
fluorescence (TADF) acrylic monomers has been designed and synthesized. When …
fluorescence (TADF) acrylic monomers has been designed and synthesized. When …