Complementary probes for the electrochemical interface

E Pastor, Z Lian, L **a, D Ecija… - Nature Reviews …, 2024 - nature.com
The functions of electrochemical energy conversion and storage devices rely on the
dynamic junction between a solid and a fluid: the electrochemical interface (EI). Many …

On the use of a constant phase element (CPE) in electrochemistry

SM Gateman, O Gharbi, HG De Melo, K Ngo… - Current Opinion in …, 2022 - Elsevier
Several techniques can be used to experimentally determine the interfacial capacitance of
an electrode, which is a crucial parameter used for quantifying the efficiency of …

Potential and electric double-layer effect in electrocatalytic urea synthesis

Q Wu, C Dai, F Meng, Y Jiao, ZJ Xu - Nature Communications, 2024 - nature.com
Electrochemical synthesis is a promising way for sustainable urea production, yet the exact
mechanism has not been fully revealed. Herein, we explore the mechanism of …

Stability of electrocatalytic OER: from principle to application

HJW Li, Y Lin, J Duan, Q Wen, Y Liu… - Chemical Society Reviews, 2024 - pubs.rsc.org
Hydrogen energy, derived from the electrolysis of water using renewable energy sources
such as solar, wind, and hydroelectric power, is considered a promising form of energy to …

Mechanistic Insights into Surfactant-Modulated Electrode–Electrolyte Interface for Steering H2O2 Electrosynthesis

Y Fan, Y Chen, W Ge, L Dong, Y Qi… - Journal of the …, 2024 - ACS Publications
Electrocatalytic reactions taking place at the electrified electrode–electrolyte interface
involve processes of proton-coupled electron transfer. Interfacial protons are delivered to the …

Understanding the complexity in bridging thermal and electrocatalytic methanation of CO 2

H Kang, J Ma, S Perathoner, W Chu, G Centi… - Chemical Society …, 2023 - pubs.rsc.org
The selective methanation of CO2 is an important research area to meet the net-zero
emission targets. Furthermore, it is crucial to develop solutions to achieve carbon neutrality …

The importance of a charge transfer descriptor for screening potential CO2 reduction electrocatalysts

S Ringe - Nature Communications, 2023 - nature.com
It has been over twenty years since the linear scaling of reaction intermediate adsorption
energies started to coin the fields of heterogeneous and electrocatalysis as a blessing and a …

Electric double layer effects in electrocatalysis: insights from ab initio simulation and hierarchical continuum modeling

P Li, Y Jiao, J Huang, S Chen - JACS Au, 2023 - ACS Publications
Structures of the electric double layer (EDL) at electrocatalytic interfaces, which are
modulated by the material properties, the electrolyte characteristics (eg, the pH, the types …

How to assess and predict electrical double layer properties. implications for electrocatalysis

CM Schott, PM Schneider, KT Song, H Yu… - Chemical …, 2024 - ACS Publications
The electrical double layer (EDL) plays a central role in electrochemical energy systems,
impacting charge transfer mechanisms and reaction rates. The fundamental importance of …

Ce4+/Ce3+ Redox-Promoted Electron Transfer for Efficient Neutral H2O2 Electrosynthesis from Two-Electron Oxygen Reduction

S Kim, YJ Sa - ACS Catalysis, 2024 - ACS Publications
Electrochemical production of H2O2 via a 2-electron oxygen reduction reaction (2e–ORR)
provides a clean alternative to the traditional industrial process. H2O2 electrosynthesis in …