Metalation of metal–organic frameworks: fundamentals and applications

HY Li, XJ Kong, SD Han, J Pang, T He… - Chemical Society …, 2024 - pubs.rsc.org
Metalation of metal–organic frameworks (MOFs) has been developed as a prominent
strategy for materials functionalization for pore chemistry modulation and property …

Advances in heterogeneous single-cluster catalysis

X Li, S Mitchell, Y Fang, J Li, J Perez-Ramirez… - Nature Reviews …, 2023 - nature.com
Heterogeneous single-cluster catalysts (SCCs) comprising atomically precise and isolated
metal clusters stabilized on appropriately chosen supports offer exciting prospects for …

Understanding the structure-performance relationship of active sites at atomic scale

R Li, D Wang - Nano Research, 2022 - Springer
Metal-based atomically dispersed catalysts have attracted more attention because of their
excellent catalytic performance and nearly 100% atom utilization. Therefore, it is very …

Emerging low-nuclearity supported metal catalysts with atomic level precision for efficient heterogeneous catalysis

X Zheng, B Li, Q Wang, D Wang, Y Li - Nano research, 2022 - Springer
Supported atomically dispersed metal catalysts (ADMCs) have received enormous attention
due to their high atom utilization efficiency, mass activity and excellent selectivity. Single …

Atomically precise electrocatalysts for oxygen reduction reaction

L Yan, P Li, Q Zhu, A Kumar, K Sun, S Tian, X Sun - Chem, 2023 - cell.com
Challenges in develo** fuel cells provide strong stimulation to develop efficient
electrocatalysts for the sluggish cathodic oxygen reduction reaction (ORR). Among various …

Single-atom platinum with asymmetric coordination environment on fully conjugated covalent organic framework for efficient electrocatalysis

Z Zhang, Z Zhang, C Chen, R Wang, M **e… - Nature …, 2024 - nature.com
Abstract Two-dimensional (2D) covalent organic frameworks (COFs) and their derivatives
have been widely applied as electrocatalysts owing to their unique nanoscale pore …

The synergistic effect of Hf-O-Ru bonds and oxygen vacancies in Ru/HfO2 for enhanced hydrogen evolution

G Li, H Jang, S Liu, Z Li, MG Kim, Q Qin, X Liu… - Nature …, 2022 - nature.com
Ru nanoparticles have been demonstrated to be highly active electrocatalysts for the
hydrogen evolution reaction (HER). At present, most of Ru nanoparticles-based HER …

Engineering single-atom sites into pore-confined nanospaces of porphyrinic metal–organic frameworks for the highly efficient photocatalytic hydrogen evolution …

Q Mo, L Zhang, S Li, H Song, Y Fan… - Journal of the American …, 2022 - ACS Publications
As a type of heterogeneous catalyst expected for the maximum atom efficiency, a series of
single-atom catalysts (SACs) containing spatially isolated metal single atoms (M-SAs) have …

Engineering semiconductor quantum dots for selectivity switch on high-performance heterogeneous coupling photosynthesis

MY Qi, M Conte, ZR Tang, YJ Xu - ACS nano, 2022 - ACS Publications
Semiconductor-based photoredox catalysis brings an innovative strategy for sustainable
organic transformation (eg, C–C/C–X bond formation), via radical coupling under mild …

Single-atom catalysts across the periodic table

SK Kaiser, Z Chen, D Faust Akl, S Mitchell… - Chemical …, 2020 - ACS Publications
Isolated atoms featuring unique reactivity are at the heart of enzymatic and homogeneous
catalysts. In contrast, although the concept has long existed, single-atom heterogeneous …