Carbon-based nanostructures as a versatile platform for tunable π-magnetism

DG de Oteyza, T Frederiksen - Journal of Physics: Condensed …, 2022 - iopscience.iop.org
Emergence of π-magnetism in open-shell nanographenes has been theoretically predicted
decades ago but their experimental characterization was elusive due to the strong chemical …

Recent progress on surface chemistry II: property and characterization

X Li, Z Xu, D Bu, J Cai, H Chen, Q Chen, T Chen… - Chinese Chemical …, 2025 - Elsevier
Surface with well-defined components and structures possesses unique electronic,
magnetic, optical and chemical properties. As a result, surface chemistry research plays a …

Nonbenzenoid high-spin polycyclic hydrocarbons generated by atom manipulation

S Mishra, S Fatayer, S Fernández, K Kaiser, D Peña… - ACS …, 2022 - ACS Publications
We report the on-surface synthesis of a nonbenzenoid triradical through dehydrogenation of
truxene (C27H18) on coinage metal and insulator surfaces. Voltage pulses applied via the …

Automated structure discovery in atomic force microscopy

B Alldritt, P Hapala, N Oinonen, F Urtev, O Krejci… - Science …, 2020 - science.org
Atomic force microscopy (AFM) with molecule-functionalized tips has emerged as the
primary experimental technique for probing the atomic structure of organic molecules on …

Tuning the diradical character of pentacene derivatives via non-benzenoid coupling motifs

T Wang, P Angulo-Portugal… - Journal of the …, 2023 - ACS Publications
The development of functional organic molecules requires structures of increasing size and
complexity, which are typically obtained by the covalent coupling of smaller building blocks …

Chemisorption-induced formation of biphenylene dimer on Ag (111)

Z Zeng, D Guo, T Wang, Q Chen, A Matěj… - Journal of the …, 2021 - ACS Publications
We report an example that demonstrates the clear interdependence between surface-
supported reactions and molecular-adsorption configurations. Two biphenyl-based …

Confined on-surface organic synthesis: Strategies and mechanisms

T Wang, J Zhu - Surface Science Reports, 2019 - Elsevier
On-surface synthesis has been one of the hottest research fields in surface science in the
last decade, owing to its great potential for bottom-up synthesis of functional molecules and …

Generating antiaromaticity in polycyclic conjugated hydrocarbons by thermally selective skeletal rearrangements at interfaces

E Pérez-Elvira, A Barragán, Q Chen, D Soler-Polo… - Nature …, 2023 - nature.com
Antiaromatic polycyclic conjugated hydrocarbons (PCHs) are attractive research targets
because of their interesting structural, electronic and magnetic properties. Unlike aromatic …

Scanning probe microscopy in probing low-dimensional carbon-based nanostructures and nanomaterials

C Zhang, Z Yi, W Xu - Materials Futures, 2022 - iopscience.iop.org
Carbon, as an indispensable chemical element on Earth, has diverse covalent bonding
ability, which enables construction of extensive pivotal carbon-based structures in multiple …

Bistability between π-diradical open-shell and closed-shell states in indeno[1,2-a]fluorene

S Mishra, M Vilas-Varela, LA Lieske, R Ortiz… - Nature Chemistry, 2024 - nature.com
Indenofluorenes are non-benzenoid conjugated hydrocarbons that have received great
interest owing to their unusual electronic structure and potential applications in nonlinear …