Carbon-based nanostructures as a versatile platform for tunable π-magnetism
Emergence of π-magnetism in open-shell nanographenes has been theoretically predicted
decades ago but their experimental characterization was elusive due to the strong chemical …
decades ago but their experimental characterization was elusive due to the strong chemical …
Recent progress on surface chemistry II: property and characterization
Surface with well-defined components and structures possesses unique electronic,
magnetic, optical and chemical properties. As a result, surface chemistry research plays a …
magnetic, optical and chemical properties. As a result, surface chemistry research plays a …
Nonbenzenoid high-spin polycyclic hydrocarbons generated by atom manipulation
We report the on-surface synthesis of a nonbenzenoid triradical through dehydrogenation of
truxene (C27H18) on coinage metal and insulator surfaces. Voltage pulses applied via the …
truxene (C27H18) on coinage metal and insulator surfaces. Voltage pulses applied via the …
Automated structure discovery in atomic force microscopy
Atomic force microscopy (AFM) with molecule-functionalized tips has emerged as the
primary experimental technique for probing the atomic structure of organic molecules on …
primary experimental technique for probing the atomic structure of organic molecules on …
Tuning the diradical character of pentacene derivatives via non-benzenoid coupling motifs
T Wang, P Angulo-Portugal… - Journal of the …, 2023 - ACS Publications
The development of functional organic molecules requires structures of increasing size and
complexity, which are typically obtained by the covalent coupling of smaller building blocks …
complexity, which are typically obtained by the covalent coupling of smaller building blocks …
Chemisorption-induced formation of biphenylene dimer on Ag (111)
We report an example that demonstrates the clear interdependence between surface-
supported reactions and molecular-adsorption configurations. Two biphenyl-based …
supported reactions and molecular-adsorption configurations. Two biphenyl-based …
Confined on-surface organic synthesis: Strategies and mechanisms
On-surface synthesis has been one of the hottest research fields in surface science in the
last decade, owing to its great potential for bottom-up synthesis of functional molecules and …
last decade, owing to its great potential for bottom-up synthesis of functional molecules and …
Generating antiaromaticity in polycyclic conjugated hydrocarbons by thermally selective skeletal rearrangements at interfaces
Antiaromatic polycyclic conjugated hydrocarbons (PCHs) are attractive research targets
because of their interesting structural, electronic and magnetic properties. Unlike aromatic …
because of their interesting structural, electronic and magnetic properties. Unlike aromatic …
Scanning probe microscopy in probing low-dimensional carbon-based nanostructures and nanomaterials
C Zhang, Z Yi, W Xu - Materials Futures, 2022 - iopscience.iop.org
Carbon, as an indispensable chemical element on Earth, has diverse covalent bonding
ability, which enables construction of extensive pivotal carbon-based structures in multiple …
ability, which enables construction of extensive pivotal carbon-based structures in multiple …
Bistability between π-diradical open-shell and closed-shell states in indeno[1,2-a]fluorene
Indenofluorenes are non-benzenoid conjugated hydrocarbons that have received great
interest owing to their unusual electronic structure and potential applications in nonlinear …
interest owing to their unusual electronic structure and potential applications in nonlinear …