Mass spectrometry-based techniques to elucidate the sugar code

M Grabarics, M Lettow, C Kirschbaum, K Greis… - Chemical …, 2021 - ACS Publications
Cells encode information in the sequence of biopolymers, such as nucleic acids, proteins,
and glycans. Although glycans are essential to all living organisms, surprisingly little is …

Probing the binding and activation of small molecules by gas-phase transition metal clusters via IR spectroscopy

A Fielicke - Chemical Society Reviews, 2023 - pubs.rsc.org
Isolated transition metal clusters have been established as useful models for extended metal
surfaces or deposited metal particles, to improve the understanding of their surface …

Interstellar polycyclic aromatic hydrocarbon molecules

AGGM Tielens - Annu. Rev. Astron. Astrophys., 2008 - annualreviews.org
Large polycyclic aromatic hydrocarbon (PAH) molecules carry the infrared (IR) emission
features that dominate the spectra of most galactic and extragalactic sources. This review …

Gas-phase infrared multiple photon dissociation spectroscopy of mass-selected molecular ions

J Oomens, BG Sartakov, G Meijer… - International Journal of …, 2006 - Elsevier
In this review, we present an overview of our recent work on the infrared spectroscopy of
mass-selected gas-phase molecular ions. The ions are stored and isolated in a quadrupole …

Infrared ion spectroscopy in a modified quadrupole ion trap mass spectrometer at the FELIX free electron laser laboratory

J Martens, G Berden, CR Gebhardt… - Review of Scientific …, 2016 - pubs.aip.org
We report on modifications made to a Paul-type quadrupole ion trap mass spectrometer and
discuss its application in infrared ion spectroscopy experiments. Main modifications involve …

Vibrational spectroscopy of bare and solvated ionic complexes of biological relevance

NC Polfer, J Oomens - Mass spectrometry reviews, 2009 - Wiley Online Library
The low density of ions in mass spectrometers generally precludes direct infrared (IR)
absorption measurements. The IR spectrum of an ion can nonetheless be obtained by …

The NASA Ames PAH IR spectroscopic database: The laboratory spectra

AL Mattioda, DM Hudgins, C Boersma… - The Astrophysical …, 2020 - iopscience.iop.org
The astronomical emission features, formerly known as the unidentified infrared bands, are
now commonly ascribed to polycyclic aromatic hydrocarbons (PAHs). The laboratory …

Experimental investigation on the formation of carbon-bearing molecules in the interstellar medium via neutral− neutral reactions

RI Kaiser - Chemical Reviews, 2002 - ACS Publications
The physical and chemical processes leading to the formation of molecules in the interstellar
medium (ISM) sthe vast voids between the starssfascinated scientists since the first detection …

Gas-phase infrared spectrum of the protonated water dimer

KR Asmis, NL Pivonka, G Santambrogio, M Brümmer… - Science, 2003 - science.org
The protonated water dimer is a prototypical system for the study of proton transfer in
aqueous solution. We report infrared photodissociation spectra of cooled H+ (H2O) 2 [and …

Cryogenic ion trap vibrational spectroscopy of hydrogen-bonded clusters relevant to atmospheric chemistry

N Heine, KR Asmis - International Reviews in Physical Chemistry, 2015 - Taylor & Francis
Recent advances in the gas phase vibrational spectroscopy of mass-selected ions are
described, highlighting experiments on hydrogen-bonded (HBed) clusters relevant to …