Metal–organic frameworks and covalent organic frameworks as disruptive membrane materials for energy-efficient gas separation

AA Knebel, J Caro - Nature Nanotechnology, 2022 - nature.com
In this Review we survey the molecular sieving behaviour of metal–organic framework
(MOF) and covalent organic framework (COF) membranes, which is different from that of …

Metal–organic network-forming glasses

N Ma, S Horike - Chemical Reviews, 2022 - ACS Publications
The crystal–liquid–glass phase transition of coordination polymers (CPs) and metal–organic
frameworks (MOFs) offers attractive opportunities as a new class of amorphous materials …

ZIF-62 glass foam self-supported membranes to address CH4/N2 separations

Z Yang, Y Belmabkhout, LN McHugh, D Ao, Y Sun… - Nature Materials, 2023 - nature.com
Membranes with ultrahigh permeance and practical selectivity could greatly decrease the
cost of difficult industrial gas separations, such as CH4/N2 separation. Advanced …

Destruction of metal–organic frameworks: positive and negative aspects of stability and lability

L Feng, KY Wang, GS Day, MR Ryder… - Chemical …, 2020 - ACS Publications
Metal–organic frameworks (MOFs), constructed from organic linkers and inorganic building
blocks, are well-known for their high crystallinity, high surface areas, and high component …

Transitioning metal–organic frameworks from the laboratory to market through applied research

AM Wright, MT Kapelewski, S Marx, OK Farha… - Nature materials, 2024 - nature.com
Metal–organic frameworks (MOFs) have captivated researchers for over 25 years, yet few
have successfully transitioned to commercial markets. This Perspective elucidates the …

Direct synthesis of amorphous coordination polymers and metal–organic frameworks

Z Lin, JJ Richardson, J Zhou, F Caruso - Nature Reviews Chemistry, 2023 - nature.com
Coordination polymers (CPs) and their subset, metal–organic frameworks (MOFs), can have
porous structures and hybrid physicochemical properties that are useful for diverse …

A MOF glass membrane for gas separation

Y Wang, H **, Q Ma, K Mo, H Mao… - Angewandte …, 2020 - Wiley Online Library
Metal–organic framework (MOF) glasses are promising candidates for membrane fabrication
due to their significant porosity, the ease of processing, and most notably, the potential to …

Structural analysis of molecular materials using the pair distribution function

MW Terban, SJL Billinge - Chemical Reviews, 2021 - ACS Publications
This is a review of atomic pair distribution function (PDF) analysis as applied to the study of
molecular materials. The PDF method is a powerful approach to study short-and …

Tailoring the solvation sheath of cations by constructing electrode front‐faces for rechargeable batteries

Z Chang, H Yang, Y Qiao, X Zhu, P He… - Advanced …, 2022 - Wiley Online Library
Solvent molecules within the solvation sheath of cations (eg, Li+, Na+, Zn2+) are easily to be
dehydrogenated especially when coupled with high‐voltage cathodes, and lead to …

Electronic devices using open framework materials

MD Allendorf, R Dong, X Feng, S Kaskel… - Chemical …, 2020 - ACS Publications
Open framework materials (OFM) constitute a large and growing class of nanoporous
crystalline structures that is attracting considerable attention for electronic device …