Designer metal–organic frameworks for size‐exclusion‐based hydrocarbon separations: progress and challenges

H Wang, Y Liu, J Li - Advanced Materials, 2020 - Wiley Online Library
The separation of hydrocarbons is of primary importance in the petrochemical industry but
remains a challenging process. Hydrocarbon separations have traditionally relied …

Rational design and synthesis of ultramicroporous metal-organic frameworks for gas separation

T Wang, E Lin, YL Peng, Y Chen, P Cheng… - Coordination Chemistry …, 2020 - Elsevier
Metal-organic frameworks (MOFs) have emerged as a new generation of porous materials
that demonstrate great promise in diverse application fields, especially gas separation, due …

Synergistic binding sites in a hybrid ultramicroporous material for one-step ethylene purification from ternary C2 hydrocarbon mixtures

P Zhang, Y Zhong, Y Zhang, Z Zhu, Y Liu, Y Su… - Science …, 2022 - science.org
One-step separation of C2H4 from ternary C2H2/C2H4/C2H6 hydrocarbon mixtures is of
great significance in the industry but is challenging due to the similar sizes and physical …

Reverse-selective metal–organic framework materials for the efficient separation and purification of light hydrocarbons

SQ Yang, TL Hu - Coordination Chemistry Reviews, 2022 - Elsevier
The separation and purification process of hydrocarbons is one of the crucial and daunting
challenges in the petrochemistry field, which is widely depended on cryogenic distillation by …

Crystal engineering of porous coordination networks to enable separation of C2 hydrocarbons

S Mukherjee, D Sensharma, KJ Chen… - Chemical …, 2020 - pubs.rsc.org
Crystal engineering, the field of chemistry that studies the design, properties, and
applications of crystals, is exemplified by the emergence over the past thirty years of porous …

Separation of alkane and alkene mixtures by metal–organic frameworks

H Wang, D Luo, E Velasco, L Yu, J Li - Journal of Materials Chemistry …, 2021 - pubs.rsc.org
The separation of alkane/alkene gas mixtures represents an important yet challenging
process in the petrochemical industry to produce valuable chemical feedstocks with …

A comprehensive review on synthetic approaches for metal-organic frameworks: From traditional solvothermal to greener protocols

D Sud, G Kaur - Polyhedron, 2021 - Elsevier
Metal-organic frameworks (MOFs) the porous materials have been primarily created by
using the inorganic metallic centers and the different organic ligands linked via coordination …

High‐Throughput Discovery of Ni(IN)2 for Ethane/Ethylene Separation

M Kang, S Yoon, S Ga, DW Kang, S Han… - Advanced …, 2021 - Wiley Online Library
Abstract Although ethylene (C2H4) is one of the most critical chemicals used as a feedstock
in artificial plastic chemistry fields, it is challenging to obtain high‐purity C2H4 gas without …

Highly Robust Microporous Metal‐Organic Frameworks for Efficient Ethylene Purification under Dry and Humid Conditions

W Liu, S Geng, N Li, S Wang, S Jia, F **… - Angewandte …, 2023 - Wiley Online Library
Two C2H6‐selective metal‐organic framework (MOF) adsorbents with ultrahigh stability,
high surface areas, and suitable pore size have been designed and synthesized for one …