In Situ X‐ray Absorption Spectroscopy of Metal/Nitrogen‐doped Carbons in Oxygen Electrocatalysis

B Wu, T Sun, Y You, H Meng, DM Morales… - Angewandte …, 2023 - Wiley Online Library
Metal/nitrogen‐doped carbons (M− N− C) are promising candidates as oxygen
electrocatalysts due to their low cost, tunable catalytic activity and selectivity, and well …

Soft x-ray absorption spectroscopy of liquids and solutions

JW Smith, RJ Saykally - Chemical reviews, 2017 - ACS Publications
X-ray absorption spectroscopy (XAS) is an electronic absorption technique for which the
initial state is a deeply buried core level. The photon energies corresponding to such …

The hidden structure of human enamel

E Beniash, CA Stifler, CY Sun, GS Jung, Z Qin… - Nature …, 2019 - nature.com
Enamel is the hardest and most resilient tissue in the human body. Enamel includes
morphologically aligned, parallel,∼ 50 nm wide, microns-long nanocrystals, bundled either …

Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries

F Lin, IM Markus, D Nordlund, TC Weng… - Nature …, 2014 - nature.com
The present study sheds light on the long-standing challenges associated with high-voltage
operation of LiNixMnxCo1− 2xO2 cathode materials for lithium-ion batteries. Using …

Amorphous calcium carbonate particles form coral skeletons

T Mass, AJ Giuffre, CY Sun, CA Stifler… - Proceedings of the …, 2017 - pnas.org
Do corals form their skeletons by precipitation from solution or by attachment of amorphous
precursor particles as observed in other minerals and biominerals? The classical model …

Revealing solid electrolyte interphase formation through interface-sensitive Operando X-ray absorption spectroscopy

JEN Swallow, MW Fraser, NJH Kneusels… - Nature …, 2022 - nature.com
The solid electrolyte interphase (SEI) that forms on Li-ion battery anodes is critical to their
long-term performance, however observing SEI formation processes at the buried electrode …

Myriad Map** of nanoscale minerals reveals calcium carbonate hemihydrate in forming nacre and coral biominerals

CA Schmidt, E Tambutté, AA Venn, Z Zou… - Nature …, 2024 - nature.com
Calcium carbonate (CaCO3) is abundant on Earth, is a major component of marine
biominerals and thus of sedimentary and metamorphic rocks and it plays a major role in the …

Surface symmetry-breaking and strain effects on orbital occupancy in transition metal perovskite epitaxial films

D Pesquera, G Herranz, A Barla, E Pellegrin… - Nature …, 2012 - nature.com
The electron occupancy of 3d-orbitals determines the properties of transition metal oxides.
This can be achieved, for example, through thin-film heterostructure engineering of AB O3 …

Determining Structure‐Activity Relationships in Oxide Derived CuSn Catalysts During CO2 Electroreduction Using X‐Ray Spectroscopy

LC Pardo Pérez, A Arndt, S Stojkovikj… - Advanced Energy …, 2022 - Wiley Online Library
The development of earth‐abundant catalysts for selective electrochemical CO2 conversion
is a central challenge. Cu Sn bimetallic catalysts can yield selective CO2 reduction toward …

Cycle-Induced Interfacial Degradation and Transition-Metal Cross-Over in LiNi0.8Mn0.1Co0.1O2–Graphite Cells

E Björklund, C Xu, WM Dose, CG Sole… - Chemistry of …, 2022 - ACS Publications
Ni-rich lithium nickel manganese cobalt (NMC) oxide cathode materials promise Li-ion
batteries with increased energy density and lower cost. However, higher Ni content is …