Structural chemistry of giant metal based supramolecules
The review presents a bird-eye view on the state of research in the field of giant
nonbiological discrete metal complexes and ions of nanometer size, which are structurally …
nonbiological discrete metal complexes and ions of nanometer size, which are structurally …
Silver nanoclusters: synthesis, structures and photoluminescence
YP **e, YL Shen, GX Duan, J Han… - Materials Chemistry …, 2020 - pubs.rsc.org
Metal nanoclusters (NCs) consist of tens to hundreds of metal atoms with a diameter of< 2
nm, and have attracted significant attention due to their unique molecule-like properties …
nm, and have attracted significant attention due to their unique molecule-like properties …
Homoleptic Alkynyl‐Protected Ag15 Nanocluster with Atomic Precision: Structural Analysis and Electrocatalytic Performance toward CO2 Reduction
We report the fabrication of homoleptic alkynyl‐protected Ag15 (C≡ C‐tBu) 12+(abbreviated
as Ag15) nanocluster and its electrocatalytic properties toward CO2 reduction reaction …
as Ag15) nanocluster and its electrocatalytic properties toward CO2 reduction reaction …
Chloride ligands on DNA-stabilized silver nanoclusters
DNA-stabilized silver nanoclusters (AgN-DNAs) are known to have one or two DNA
oligomer ligands per nanocluster. Here, we present the first evidence that AgN-DNA species …
oligomer ligands per nanocluster. Here, we present the first evidence that AgN-DNA species …
Small symmetry-breaking triggering large chiroptical responses of Ag70 nanoclusters
XM Luo, CH Gong, F Pan, Y Si, JW Yuan… - Nature …, 2022 - nature.com
The origins of the chiroptical activities of inorganic nanostructures have perplexed scientists,
and deracemization of high-nuclearity metal nanoclusters (NCs) remains challenging. Here …
and deracemization of high-nuclearity metal nanoclusters (NCs) remains challenging. Here …
Fluorescence resonance energy transfer in atomically precise metal nanoclusters by cocrystallization-induced spatial confinement
Understanding the fluorescence resonance energy transfer (FRET) of metal nanoparticles at
the atomic level has long been a challenge due to the lack of accurate systems with definite …
the atomic level has long been a challenge due to the lack of accurate systems with definite …
An Ultrastable 155‐Nuclei Silver Nanocluster Protected by Thiacalix [4] arene and Cyclohexanethiol for Photothermal Conversion
Thiacalix [4] arenes have emerged as a family of macrocyclic ligands to protect metal
nanoparticles, but it remains a great challenge to solve the mystery of their structures at the …
nanoparticles, but it remains a great challenge to solve the mystery of their structures at the …
Atomically precise gold nanoclusters at the molecular-to-metallic transition with intrinsic chirality from surface layers
The advances in determining the total structure of atomically precise metal nanoclusters
have prompted extensive exploration into the origins of chirality in nanoscale systems. While …
have prompted extensive exploration into the origins of chirality in nanoscale systems. While …
Light-activated intercluster conversion of an atomically precise silver nanocluster
Noble metal nanoclusters protected with carboranes, a 12-vertex, nearly icosahedral boron–
carbon framework system, have received immense attention due to their different …
carbon framework system, have received immense attention due to their different …
Intra-cluster growth meets inter-cluster assembly: The molecular and supramolecular chemistry of atomically precise nanoclusters
X Kang, M Zhu - Coordination Chemistry Reviews, 2019 - Elsevier
The molecular and supramolecular chemistry of atomically precise nanoclusters
encompasses intra-cluster growth, inter-cluster assembly, and cluster-based host-guest …
encompasses intra-cluster growth, inter-cluster assembly, and cluster-based host-guest …