Fine metal clusters have attracted much attention from the viewpoints of both basic and
applied science for many years because of their unique physical/chemical properties and …

Although thiolated, reduced Group 11 metal nanoclusters with atomic monodispersity have
been repeatedly reported in the past decade, their Pd analogues have not been reported …

Subnanometer noble metal clusters have enormous potential, mainly for catalytic
applications. Because a difference of only one atom may cause significant changes in their …

Constructing ambient‐stable, single‐atom‐layered metal‐based materials with atomic
precision and understanding their underlying stability mechanisms are challenging. Here …

In the global attempt to reduce carbon footprint toward sustainability, the chemical and
petrochemical industry faces the problem to replace the fossil feedstock with renewable …

To propose the concept of single-atom-kernelled nanocluster, we synthesized a Pd-based
trimetal nanocluster with a single-Ag atom-kernel for the first time by introducing some steric …

Practical electrochemical water splitting and carbon-dioxide reduction are desirable for a
sustainable energy society. In particular, facilitating the oxygen evolution reaction (OER, the …

Atomically precise Pd-thiolate clusters are well-known for their well-defined structures and
diverse applications involving catalysis, sensors, and biomedicine. While many of these …

Structural isomerization is an important concept in organic chemistry and it is recently found
to be applicable to thiolated gold nanoparticles. However, to the best of our knowledge, the …

The development of renewable energy technologies is critical for reducing global carbon
emissions. Water splitting offers a promising renewable energy mechanism by converting …