Oligomerization of higher α-olefins to poly (α-olefins)
Abstract Poly (α-olefin)(PAO) type synthetic lubricants have attracted considerable interest in
both the academic and industrial sectors in the last two decades. The continuous growth of …
both the academic and industrial sectors in the last two decades. The continuous growth of …
Fair look at coordination oligomerization of higher α-olefins
I Nifant'ev, P Ivchenko - Polymers, 2020 - mdpi.com
Coordination catalysis is a highly efficient alternative to more traditional acid catalysis in the
oligomerization of α-olefins. The distinct advantage of transition metal-based catalysts is the …
oligomerization of α-olefins. The distinct advantage of transition metal-based catalysts is the …
Methods for producing metal-containing sulfated activator-supports
Q Yang, MP McDaniel, TR Crain - US Patent 8,309,485, 2012 - Google Patents
The present invention provides metal-containing Sulfated activator-Supports, and
polymerization catalyst compositions employing these activator-supports. Methods for …
polymerization catalyst compositions employing these activator-supports. Methods for …
Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches
Q Yang, MP McDaniel, JL Martin, TR Crain… - US Patent …, 2012 - Google Patents
The present invention provides a polymerization process Which is conducted by contacting
an ole? n monomer and at least one ole? n comonomer in the presence of hydrogen and a …
an ole? n monomer and at least one ole? n comonomer in the presence of hydrogen and a …
A competetive way to low-viscosity PAO base stocks via heterocene-catalyzed oligomerization of dec-1-ene
IE Nifant'ev, AA Vinogradov, AA Vinogradov… - Molecular …, 2022 - Elsevier
Hydrogenated oligomers of higher α-olefins (primarily, dec-1-ene) represent base stocks for
high-quality polyolefin oils (PAOs), transmission fluids, lubricants and greases. Competitive …
high-quality polyolefin oils (PAOs), transmission fluids, lubricants and greases. Competitive …
Nano-linked metallocene catalyst compositions and their polymer products
RE Murray, KC Jayaratne, Q Yang, JL Martin - US Patent 8,080,681, 2011 - Google Patents
US8080681B2 - Nano-linked metallocene catalyst compositions and their polymer products -
Google Patents US8080681B2 - Nano-linked metallocene catalyst compositions and their …
Google Patents US8080681B2 - Nano-linked metallocene catalyst compositions and their …
MAO-and Borate-Free Activating Supports for Group 4 Metallocene and Post-Metallocene Catalysts of α-Olefin Polymerization and Oligomerization
IE Nifant'ev, PD Komarov, OD Kostomarova… - Polymers, 2023 - mdpi.com
Modern industry of advanced polyolefins extensively uses Group 4 metallocene and post-
metallocene catalysts. High-throughput polyolefin technologies demand the use of …
metallocene catalysts. High-throughput polyolefin technologies demand the use of …
Dual metallocene catalysts for polymerization of bimodal polymers
Q Yang, KC Jayaratne, MD Jensen… - US Patent …, 2012 - Google Patents
This invention relates to catalyst compositions, methods, and polymers encompassing at
least one first Group 4 metal locene compound comprising bridging m-cyclopentadienyl type …
least one first Group 4 metal locene compound comprising bridging m-cyclopentadienyl type …
Methylenealkane-based low-viscosity ester oils: synthesis and outlook
I Nifant'ev, V Bagrov, A Vinogradov, A Vinogradov… - Lubricants, 2020 - mdpi.com
Both Group 4 poly-α-olefin (PAO) and Group 5 ester oil basestocks are used in formulations
of synthetic engine oils, transmission fluids, and lubricants with leading characteristics such …
of synthetic engine oils, transmission fluids, and lubricants with leading characteristics such …
Dual metallocene catalyst systems for decreasing melt index and increasing polymer production rates
AP Masino, RE Murray, Q Yang, SJ Secora… - US Patent …, 2012 - Google Patents
The present invention provides dual catalyst Systems and polymerization processes
employing these dual catalyst sys tems. The disclosed polymerization processes can …
employing these dual catalyst sys tems. The disclosed polymerization processes can …