Diverse metal–organic complexes (MOCs), shaped as rectangles, triangles, hexagons,
prisms, and cages, can be formed by coordination between metal ions (Pt, Pd, Ru, Rh, Ir, Zn …

Over the past few decades, supramolecular chirality in discrete metallosupramolecular
architectures has received considerable attention. In this review, a comprehensive summary …

Due to the inherent difficulties in achieving a defined and exclusive formation of
multicomponent assemblies against entropic predisposition, we present the rational …

In the supramolecular chemistry field, coordination-driven self-assembly has provided the
basis for tremendous growth across many subdisciplines, spanning from fundamental …

The design of structurally defined heteroleptic coordination cages is a challenging task, and
only few examples are known to date. Here we describe a selection approach that allowed …

The biomedical application of discrete supramolecular metal-based structures, including
supramolecular coordination complexes (SCCs), is still an emergent field of study. However …

Highlights•TNBC is an unmet medical need with poor survival rates and no targeted
therapy.•TNBC resists conventional chemotherapy and surgical strategies.•A review of 121 …

Metallosupramolecular architectures are beginning to be exploited for a range of
applications including drug delivery, catalysis, molecular recognition, and sensing. For the …

A strategy is presented that enables the quantitative assembly of a heterobimetallic [PdPtL4]
4+ cage. The presence of two different metal ions (PdII and PtII) with differing labilities …

With increasing interest in the potential utility of metallo-supramolecular architectures for
applications as diverse as catalysis and drug delivery, the ability to develop more complex …