Carbon-based materials for electrochemical dechlorination

G Gan, G Hong, W Zhang - Nano Research, 2023 - Springer
Electrochemical dechlorination reaction (EDR) is a promising, environmentally friendly, and
economically profitable technology for treating chlorinated organic pollutants. For efficient …

Insights into electroreductive dehalogenation mechanisms of chlorinated environmental pollutants

H Yin, X Cao, C Lei, W Chen, B Huang - ChemElectroChem, 2020 - Wiley Online Library
The electroreductive cleavage of carbon‐chloro bonds has attracted increasing attention
from both environmental and mechanistic points of view over the past decades, taking into …

Single-Ni-atom catalyzes aqueous phase electrochemical reductive dechlorination reaction

Y Xu, Z Yao, Z Mao, M Shi, X Zhang, F Cheng… - Applied Catalysis B …, 2020 - Elsevier
Electrochemical dechlorination offers a promising strategy to convert refractory chlorinated
organic pollutants (COPs) to biodegradable chlorine-free organics under mild conditions. In …

Alachlor dechlorination prior to an electro-Fenton process: Influence on the biodegradability of the treated solution

YY Lou, F Geneste, I Soutrel, A Amrane… - Separation and …, 2020 - Elsevier
This study investigates alachlor herbicide removal by electro-Fenton (EF) process with and
without a previous dechlorination step by electro-reduction (ER-EF). The objective is to …

Investigating the role of ligand electronics on stabilizing electrocatalytically relevant low-valent Co (I) intermediates

DP Hickey, C Sandford, Z Rhodes… - Journal of the …, 2019 - ACS Publications
Cobalt complexes have shown great promise as electrocatalysts in applications ranging
from hydrogen evolution to C–H functionalization. However, the use of such complexes often …

Electrocatalytic dechlorination of dichloromethane in water using a heterogenized molecular copper complex

CK Williams, GA McCarver, A Lashgari… - Inorganic …, 2021 - ACS Publications
The remediation of organohalides from water is a challenging process in environment
protection and water treatment. Herein, we report a molecular copper (I) complex with two …

Programmable Monodisperse Glyco-Multivalency Using Self-Assembled Coordination Cages as Scaffolds

C Pritchard, M Ligorio, GD Jackson… - … applied materials & …, 2023 - ACS Publications
The multivalent presentation of glycans leads to enhanced binding avidity to lectins due to
the cluster glycoside effect. Most materials used as scaffolds for multivalent glycan arrays …

C–Cl Bond Activation at Rotated vs Unrotated Dinuclear Site Related to [FeFe]-Hydrogenases

L Chatelain, F Arrigoni, P Schollhammer… - Inorganic …, 2023 - ACS Publications
The novel dinuclear complex related to the [FeFe]-hydrogenases active site,[Fe2 (μ-pdt)(κ2-
dmpe) 2 (CO) 2](1), is highly reactive toward chlorinated compounds CH x Cl4–x (x= 1, 2) …

Exploring the synergy between copper electrolytes and molecularly engineered thiocyanate‐free cyclometalated ruthenium sensitizers for dye‐sensitized solar cells

S MM, SC Pradhan, AS George, N PR… - Photochemistry and …, 2024 - Wiley Online Library
Two novel cyclometalated ruthenium complexes, RC‐4 and RC‐5, featuring 1‐
phenylisoquinoline and phenyl quinazoline as ancillary ligands, respectively, were …

Catalytic electrochemical pre-treatment for the degradation of persistent organic pollutants

F Geneste - Current Opinion in Electrochemistry, 2018 - Elsevier
Electrochemical advanced oxidation processes have been widely explored for the total
degradation of biorecalcitrant compounds such as some pesticides and pharmaceuticals …