Weak polyelectrolytes as nanoarchitectonic design tools for functional materials: a review of recent achievements

NM Sanchez-Ballester, F Sciortino, SH Mir, G Rydzek - Molecules, 2022 - mdpi.com
The ionization degree, charge density, and conformation of weak polyelectrolytes can be
adjusted through adjusting the pH and ionic strength stimuli. Such polymers thus offer a …

Scalable Fabrication of Reversible Antifouling Block Copolymer Coatings via Adsorption Strategies

AMC Maan, CN Graafsma, AH Hofman… - … Applied Materials & …, 2023 - ACS Publications
Fouling remains a widespread challenge as its nonspecific and uncontrollable character
limits the performance of materials and devices in numerous applications. Although many …

Hydrophobically modified complex coacervates for designing aqueous pressure-sensitive adhesives

L van Westerveld, JE Sayed, M de Graaf, AH Hofman… - Soft Matter, 2023 - pubs.rsc.org
The rheology of complex coacervates can be elegantly tuned via the design and control of
specific non-covalent hydrophobic interactions between the complexed polymer chains. The …

Sulfonated Block Copolymers: Synthesis, Chemical Modification, Self-Assembly Morphologies, and Recent Applications

CI Piñón-Balderrama, C Leyva-Porras… - Polymers, 2022 - mdpi.com
Scientific research based on the self-assembly behavior of block copolymers (BCs)
comprising charged-neutral segments has emerged as a novel strategy mainly looking for …

Strong anionic/charge-neutral block copolymers from Cu (0)-mediated reversible deactivation radical polymerization

T Pelras, AH Hofman, LMH Germain, AMC Maan… - …, 2022 - ACS Publications
Despite recent developments in controlled polymerization techniques, the straightforward
synthesis of block copolymers that feature both strong anionic and charge-neutral segments …

One-Pot Synthesis of Strong Anionic/Charge-Neutral Amphiphilic Block Copolymers

T Pelras, A Eisenga, G Érsek, A Altomare… - ACS Macro …, 2023 - ACS Publications
Despite the ever more versatile polymerization techniques that are becoming available, the
synthesis of macromolecules with tailored functionalities can remain a lengthy endeavor …

Effect of Polyelectrolyte Charge Density on the Linear Viscoelastic Behavior and Processing of Complex Coacervate Adhesives

L van Westerveld, T Pelras, AH Hofman, K Loos… - …, 2024 - ACS Publications
It is well-known that the phase behavior and physicochemical and adhesive properties of
complex coacervates are readily tuneable with the salt concentration of the medium. For …

[HTML][HTML] Temperature-responsive polyelectrolyte complexes for bio-inspired underwater adhesives

IA van Hees, AH Hofman, M Dompé… - European Polymer …, 2020 - Elsevier
Adhesive proteins of marine organisms contain significant amounts of hydrophobic amino
acids. Therefore, inter-and intramolecular hydrophobic interactions are expected to play an …

Protected Poly (3-sulfopropyl methacrylate) Copolymers: Synthesis, Stability, and Orthogonal Deprotection

AH Hofman, M Pedone, M Kamperman - ACS Polymers Au, 2021 - ACS Publications
Because of their permanent charge, strong polyelectrolytes remain challenging to
characterize, in particular, when they are combined with hydrophobic features. For this …

Influence of counterions on the thermal and solution properties of strong polyelectrolytes

T Pelras, JE Sayed, J Pierik, A Giuntoli… - Polymer …, 2025 - pubs.rsc.org
Strong polyelectrolytes (ie, macromolecules whose charge density is independent of the
medium's pH) are invaluable assets in the soft matter toolbox, as they can readily disperse in …