Molecular cavity for catalysis and formation of metal nanoparticles for use in catalysis

R Saha, B Mondal, PS Mukherjee - Chemical Reviews, 2022 - ACS Publications
The employment of weak intermolecular interactions in supramolecular chemistry offers an
alternative approach to project artificial chemical environments like the active sites of …

Design and applications of water-soluble coordination cages

EG Percástegui, TK Ronson, JR Nitschke - Chemical Reviews, 2020 - ACS Publications
Compartmentalization of the aqueous space within a cell is necessary for life. In similar
fashion to the nanometer-scale compartments in living systems, synthetic water-soluble …

Chiral covalent organic frameworks: design, synthesis and property

X Han, C Yuan, B Hou, L Liu, H Li, Y Liu… - Chemical Society …, 2020 - pubs.rsc.org
Covalent organic frameworks (COFs) are constructed using reticular chemistry with the
building blocks being connected via covalent bonds and have emerged as a new series of …

Recent developments in the construction and applications of platinum-based metallacycles and metallacages via coordination

Y Sun, C Chen, J Liu, PJ Stang - Chemical Society Reviews, 2020 - pubs.rsc.org
Coordination-driven suprastructures have attracted much interest due to their unique
properties. Among these structures, platinum-based architectures have been broadly …

Catalytic reactions within the cavity of coordination cages

Y Fang, JA Powell, E Li, Q Wang, Z Perry… - Chemical Society …, 2019 - pubs.rsc.org
Natural enzymes catalyze reactions in their substrate-binding cavities, exhibiting high
specificity and efficiency. In an effort to mimic the structure and functionality of enzymes …

Functional supramolecular systems: Design and applications

IS Antipin, MV Alfimov, VV Arslanov… - Russian Chemical …, 2021 - iopscience.iop.org
The interest in functional supramolecular systems for the design of innovative materials and
technologies, able to fundamentally change the world, is growing at a high pace. The huge …

Yolk–Shell and Hollow Zr/Ce-UiO-66 for Manipulating Selectivity in Tandem Reactions and Photoreactions

HH He, JP Yuan, PY Cai, KY Wang… - Journal of the …, 2023 - ACS Publications
One of the hallmarks of multicomponent metal–organic frameworks (MOFs) is to finely tune
their active centers to achieve product selectivity. In particular, obtaining bimetallic MOF …

Photooxidase mimicking with adaptive coordination molecular capsules

DN Yan, LX Cai, PM Cheng, SJ Hu… - Journal of the …, 2021 - ACS Publications
One important feature of enzyme catalysis is the induced-fit conformational change after
binding substrates. Herein, we report a biomimetic water-soluble molecular capsule …

Multiple-stimuli fluorescent responsive metallo-organic helicated cage arising from monomer and excimer emission

Z Zhang, Q Bai, Z Zhai, Q Long, E Han, H Zhao… - Nature …, 2024 - nature.com
Effectively regulating monomer and excimer emission in a singular supramolecular
luminous platform is challenging due to high difficulty of precise control over its aggregation …

Isoreticular Preparation of Tetraphenylethylene‐based Multicomponent Metallacages towards Light‐Driven Hydrogen Production

C Mu, L Zhang, G Li, Y Hou, H Liu, Z Zhang… - Angewandte …, 2023 - Wiley Online Library
Multicomponent metallacages can integrate the functions of their different building blocks to
achieve synergetic effects for advanced applications. Herein, based on metal‐coordination …