Molecular cavity for catalysis and formation of metal nanoparticles for use in catalysis
The employment of weak intermolecular interactions in supramolecular chemistry offers an
alternative approach to project artificial chemical environments like the active sites of …
alternative approach to project artificial chemical environments like the active sites of …
Design and applications of water-soluble coordination cages
EG Percástegui, TK Ronson, JR Nitschke - Chemical Reviews, 2020 - ACS Publications
Compartmentalization of the aqueous space within a cell is necessary for life. In similar
fashion to the nanometer-scale compartments in living systems, synthetic water-soluble …
fashion to the nanometer-scale compartments in living systems, synthetic water-soluble …
Chiral covalent organic frameworks: design, synthesis and property
Covalent organic frameworks (COFs) are constructed using reticular chemistry with the
building blocks being connected via covalent bonds and have emerged as a new series of …
building blocks being connected via covalent bonds and have emerged as a new series of …
Recent developments in the construction and applications of platinum-based metallacycles and metallacages via coordination
Coordination-driven suprastructures have attracted much interest due to their unique
properties. Among these structures, platinum-based architectures have been broadly …
properties. Among these structures, platinum-based architectures have been broadly …
Catalytic reactions within the cavity of coordination cages
Natural enzymes catalyze reactions in their substrate-binding cavities, exhibiting high
specificity and efficiency. In an effort to mimic the structure and functionality of enzymes …
specificity and efficiency. In an effort to mimic the structure and functionality of enzymes …
Functional supramolecular systems: Design and applications
IS Antipin, MV Alfimov, VV Arslanov… - Russian Chemical …, 2021 - iopscience.iop.org
The interest in functional supramolecular systems for the design of innovative materials and
technologies, able to fundamentally change the world, is growing at a high pace. The huge …
technologies, able to fundamentally change the world, is growing at a high pace. The huge …
Yolk–Shell and Hollow Zr/Ce-UiO-66 for Manipulating Selectivity in Tandem Reactions and Photoreactions
One of the hallmarks of multicomponent metal–organic frameworks (MOFs) is to finely tune
their active centers to achieve product selectivity. In particular, obtaining bimetallic MOF …
their active centers to achieve product selectivity. In particular, obtaining bimetallic MOF …
Photooxidase mimicking with adaptive coordination molecular capsules
DN Yan, LX Cai, PM Cheng, SJ Hu… - Journal of the …, 2021 - ACS Publications
One important feature of enzyme catalysis is the induced-fit conformational change after
binding substrates. Herein, we report a biomimetic water-soluble molecular capsule …
binding substrates. Herein, we report a biomimetic water-soluble molecular capsule …
Multiple-stimuli fluorescent responsive metallo-organic helicated cage arising from monomer and excimer emission
Z Zhang, Q Bai, Z Zhai, Q Long, E Han, H Zhao… - Nature …, 2024 - nature.com
Effectively regulating monomer and excimer emission in a singular supramolecular
luminous platform is challenging due to high difficulty of precise control over its aggregation …
luminous platform is challenging due to high difficulty of precise control over its aggregation …
Isoreticular Preparation of Tetraphenylethylene‐based Multicomponent Metallacages towards Light‐Driven Hydrogen Production
Multicomponent metallacages can integrate the functions of their different building blocks to
achieve synergetic effects for advanced applications. Herein, based on metal‐coordination …
achieve synergetic effects for advanced applications. Herein, based on metal‐coordination …