Alkane hydroxylation by a nonheme iron catalyst that challenges the heme paradigm for oxygenase...

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Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts

S Rana, JP Biswas, S Paul, A Paik… - Chemical Society Reviews, 2021 - pubs.rsc.org
In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …
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Design of molecular water oxidation catalysts with earth-abundant metal ions

M Kondo, H Tatewaki, S Masaoka - Chemical Society Reviews, 2021 - pubs.rsc.org
The four-electron oxidation of water (2H2O→ O2+ 4H++ 4e−) is considered the main
bottleneck in artificial photosynthesis. In nature, this reaction is catalysed by a Mn4CaO5 …
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Iron-and cobalt-catalyzed C (sp 3)–H bond functionalization reactions and their application in organic synthesis

Y Liu, T You, [PDF] uca.es

Trap** a Highly Reactive Nonheme Iron Intermediate That Oxygenates Strong C H Bonds with Stereoretention

J Serrano-Plana, WN Oloo… - Journal of the …, 2015 - ACS Publications
An unprecedentedly reactive iron species (2) has been generated by reaction of excess
peracetic acid with a mononuclear iron complex [FeII (CF3SO3) 2 (PyNMe3)](1) at cryogenic …
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