Recent advances in 3d-4f magnetic complexes with several types of non-carboxylate organic ligands

HS Wang, K Zhang, Y Song, ZQ Pan - Inorganica Chimica Acta, 2021 - Elsevier
Since 1993, single molecule magnets (SMMs) have received a wide attention for their
potential applications in high-density information storage device, quantum computer and …

Why lanthanide Er III SIMs cannot possess huge energy barriers: a theoretical investigation

F Lu, MM Ding, JX Li, BL Wang, YQ Zhang - Dalton Transactions, 2020 - pubs.rsc.org
Complete active space self-consistent field (CASSCF) combined with restricted active space
spin interaction with spin–orbit coupling (RASSI-SO) was used to probe why single-ion …

Chiral 4f and 3d-4f Complexes from Enantiopure Salen-Type Schiff Base Ligands

CP Raptopoulou - Crystals, 2024 - mdpi.com
This review summarizes the structural characteristics and physicochemical properties of
chiral 4f and 3d-4f complexes based on enantiopure salen-type Schiff base ligands. The …

Circularly polarized luminescence and magneto-optic effects from chiral Dy (III) single molecule magnets

H Huang, R Sun, XF Wu, Y Liu, JZ Zhan… - Dalton …, 2023 - pubs.rsc.org
A new pair of multifunctional Zn (II)–Dy (III) enantiomers based on the chiral Schiff-base
ligands [R, R-ZnLDy (H2O)(NO3) 3](1R2R-ZnDy) and [S, S-ZnLDy (H2O)(NO3) 3](1S2S …

Insight into ferromagnetic interactions in Cu II–Ln III dimers with a compartmental ligand

A Panja, S Paul, E Moreno-Pineda, R Herchel… - Dalton …, 2024 - pubs.rsc.org
In the last two decades, efforts have been devoted to obtaining insight into the magnetic
interactions between CuII and LnIII utilizing experimental and theoretical means …

The effect of co-ligands on the performance of single-molecule magnet behaviours in a family of linear trinuclear Zn–Dy–Zn complexes with a compartmental Schiff …

R Nandy, Z Jagličić, NC Jana, P Brandão… - Dalton …, 2024 - pubs.rsc.org
We present herein magneto-structural studies of three heterometallic Zn2Dy
complexes:[Zn2Dy (L) 2Cl2 (H2O)](ClO4)· 4H2O (1),[Zn2Dy (L) 2Br2 (H2O)](ClO4)· 4H2O (2) …

Field-Induced Slow Relaxation of the Magnetization in Two Families of [MIILnIII] Complexes

E Costa-Villén, M Font-Bardia, J Mayans… - Crystal Growth & …, 2024 - ACS Publications
A family of discrete dinuclear complexes [MIILnIII](M= Cu, Ni and Ln= Ce, Gd, Tb, Dy, Er, Yb)
has been synthesized from the use of the compartmental Schiff base ligand H4L (3, 3′-((1 …

Influence of the Different Types of Auxiliary Noncarboxylate Organic Ligands on the Topologies and Magnetic Relaxation Behavior of Zn–Dy Heterometallic Single …

HS Wang, K Zhang, J Wang, ZB Hu, Z Zhang… - Inorganic …, 2021 - ACS Publications
In this work, we first synthesized a Zn–Dy complex,[Zn6Dy2 (L) 6 (tea) 2 (CH3OH) 2]·
6CH3OH· 8H2O (H2L= N-3-methoxysalicylidene-2-amino-3-hydroxypyridine, teaH3 …

Combined experimental and theoretical studies on a series of mononuclear Ln III single-molecule magnets: dramatic influence of remote substitution on the magnetic …

K Pramanik, Z Jagličić, R Herchel, P Brandão… - Dalton …, 2023 - pubs.rsc.org
A series of LnIII complexes of general formula [Ln (H2L1) 2 (NO3) 2 (H2O)](NO3)(1–5)[Ln=
Dy (1), Tb (2) Ho (3), Er (4), and Yb (5)] and an analogous DyIII complex with ligand …

Correlating the axial Zero Field Splitting with the slow magnetic relaxation in Gd III SIMs

J Mayans, A Escuer - Chemical Communications, 2021 - pubs.rsc.org
Correlating the axial Zero Field Splitting with the slow magnetic relaxation in Gd III SIMs -
Chemical Communications (RSC Publishing) DOI:10.1039/D0CC07474H Royal Society of …