Synergetic spin singlet–quintet switching and luminescence in mononuclear Fe (ii) 1, 3, 4-oxadiazole tetradentate chelates with NCBH 3 co-ligand
S Sundaresan, JG Becker, J Eppelsheimer… - Dalton …, 2023 - pubs.rsc.org
We report the multi-step synthesis of the tetradentate 2-(naphthalen-2-yl)-5-[N, N-bis (2-
pyridylmethyl) aminomethyl]-1, 3, 4-oxadiazole ligand (LTetra-ODA) along with its …
pyridylmethyl) aminomethyl]-1, 3, 4-oxadiazole ligand (LTetra-ODA) along with its …
Incorporation of switchable inorganic building blocks into heterometallic coordination polymers
MG Robb, S Brooker - Crystal Growth & Design, 2023 - ACS Publications
A new terpyridine-based ligand with a pyridyl-1, 2, 4-triazoyl bidentate pocket “out the back”
has been used to synthesize monometallic CoII, FeII, and RuII complexes where the …
has been used to synthesize monometallic CoII, FeII, and RuII complexes where the …
[HTML][HTML] Compressed Jahn-Teller octahedra and spin quintet-triplet switching in coordinatively elastic manganese (III) complexes
Complex assembly preferences and resultant spin state choice and Jahn-Teller distortion
mode in twelve Mn (III) complexes of varying nuclearity with Schiff base chelate ligands of …
mode in twelve Mn (III) complexes of varying nuclearity with Schiff base chelate ligands of …
Effect of Methoxy Ligand-Substituent and NCE Coligands in Tuning T1/2 of Coordinatively Elastic Fe(II) Spin Crossover Complexes
S Sundaresan, J Kiehl, LM Carrella… - Crystal Growth & …, 2023 - ACS Publications
We report the multistep synthesis of a thiadiazole based ligand (L OMe-Nap) with a methoxy
substituent in the six-position of the naphthalene ring, along with the corresponding iron …
substituent in the six-position of the naphthalene ring, along with the corresponding iron …
Spin state solvomorphism in a series of rare S= 1 manganese (III) complexes
Structural, magnetic and spectroscopic data of four complex salts,[Mn (napsal2323)] NTf2,
1,[Mn (napsal2323)] ClO4, 2,[Mn (napsal2323)] BF4, 3 and [Mn (napsal2323)] NO3, 4, of the …
1,[Mn (napsal2323)] ClO4, 2,[Mn (napsal2323)] BF4, 3 and [Mn (napsal2323)] NO3, 4, of the …
Crystallographic Detection of the Spin State in FeIII Complexes
We report a single example of thermal spin crossover in a series of FeIII complexes,[FeIII (R-
sal2323)]+, which typically stabilize the low-spin (S= 1/2) state. Single-crystal X-ray …
sal2323)]+, which typically stabilize the low-spin (S= 1/2) state. Single-crystal X-ray …
Monomeric Fe (III)‐Hydroxo and Fe (III)‐Aqua Complexes Display Oxidative Asynchronous Hydrogen Atom Abstraction Reactivity
This paper presents the synthesis and characterization of a series of novel monomeric aqua‐
ligated iron (III) complexes,[FeIII (L5R)(OH2)] 2+(R= OMe, H, Cl, NO2), supported by an …
ligated iron (III) complexes,[FeIII (L5R)(OH2)] 2+(R= OMe, H, Cl, NO2), supported by an …
Spin crossover behaviour of asymmetrical iron (iii) Schiff base complexes from ethylenediamine
D Tesfaye, M Gebrezgiabher, J Braun, T Sani… - New Journal of …, 2024 - pubs.rsc.org
Novel asymmetrical Fe (III) Schiff base coordination complexes, with the N4O2 coordination
environment, exhibiting abrupt spin crossover (SCO) behaviour with a wide hysteresis loop …
environment, exhibiting abrupt spin crossover (SCO) behaviour with a wide hysteresis loop …
Synthesis and applications of new spin crossover compounds
T Kitazawa - Crystals, 2019 - mdpi.com
The spin crossover (SCO) between multi-stable states in transition metal material is one of
the attractive molecular switching phenomena which is responsive to various external stimuli …
the attractive molecular switching phenomena which is responsive to various external stimuli …
Crystallographic Evidence of η1-Coordination of Bulky Aminopyridine in Halide-Containing Iron (II) Complexes
A Noor - Crystals, 2022 - mdpi.com
Reaction of N-(2, 6-diisopropylphenyl)-[6-(2, 4, 6-triisopropylphenyl)-pyridine-2-yl]-amine
(ApH) in equimolar ratio with anhydrous FeBr2 and FeI2 in tetrahydrofuran (THF) afforded …
(ApH) in equimolar ratio with anhydrous FeBr2 and FeI2 in tetrahydrofuran (THF) afforded …