In mixed-valence (MV) systems essentially identical, more or less electronically coupled,
redox centres are brought into formally different oxidation states by removal or addition of an …

In this review, the electronic and structural properties of different organometallic wires
containing the (dppe) Cp* Fe organometallic electrophore are thoroughly discussed. Results …

The concept of a molecular-based electronic technology has been evolving for over 50
years, and the development of molecular designs for such components over this period has …

In this Perspective, we highlight the non-innocent behaviour of the bridging ligand in
organometallic polynuclear metallic complexes displaying metal-carbon σ bonds between …

A series of bimetallic ruthenium complexes [{Ru (dppe) Cp*} 2 (μ-C CArC C)] featuring
diethynylaromatic bridging ligands (Ar= 1, 4-phenylene, 1, 4-naphthylene, 9, 10-anthrylene) …

This study reports the isolation and the structural (X-ray), UV− vis, and NMR characterization
of a series of electron-rich Ru (II) acetylide complexes of the formula (η2-dppe)(η5-C5Me5) …

Dinuclear acetylide‐type complexes bridged by a photochromic dithienylethene unit
(DTE),[Y C C DTE C C Y] 1 (Y={MCp*(dppe)}; Cp*= pentamethylcyclopentadienyl …

The divinylphenylene-bridged diruthenium complexes (E, E)-[{(P i Pr3) 2 (CO) ClRu} 2 (μ-
HC CHC6H4CH CH-1, 3)](m-2) and (E, E)-[{(P i Pr3) 2 (CO) ClRu} 2 (μ-HC CHC6H4CH CH …

We herein describe a systematic account of mononuclear ruthenium vinyl complexes
L−{Ru}− CH CH− R where the phosphine ligands at the (PR '3) 2Ru (CO) Cl {Ru} moiety, the …

A series of 2, 5-di-and 2, 3, 4, 5-tetraferrocenyl-substituted thiophenes, furans, and pyrroles
were synthesized using the Negishi C, C cross-coupling protocol. The electronic and …