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Surface functionalization of inorganic nanoparticles with ligands: a necessary step for their utility
The importance of organic ligands in protecting inorganic nanoparticles and thus imparting
the needed stabilization as colloidal dispersions was realised many years ago. Currently …
the needed stabilization as colloidal dispersions was realised many years ago. Currently …
The role and fate of cap** ligands in colloidally prepared metal nanoparticle catalysts
Metal nanoparticles have received intense scientific attention in the field of catalysis. Precise
engineering of nanomaterials' size, shape and surface composition, including adsorbed …
engineering of nanomaterials' size, shape and surface composition, including adsorbed …
Opportunities for Electrocatalytic CO2 Reduction Enabled by Surface Ligands
To achieve high selectivity in enzyme catalysis, nature carefully controls both the catalyst
active site and the pocket or environment that mediates access and the geometry of a …
active site and the pocket or environment that mediates access and the geometry of a …
Perspective of surfactant‐free colloidal nanoparticles in heterogeneous catalysis
Due to material gaps and synthesis‐related cross‐correlations in heterogeneous catalysis,
chemists and physicists are constantly motivated to develop novel catalyst preparation …
chemists and physicists are constantly motivated to develop novel catalyst preparation …
Functionalization of Platinum Nanoparticles with l-Proline: Simultaneous Enhancements of Catalytic Activity and Selectivity
I Schrader, J Warneke, J Backenköhler… - Journal of the American …, 2015 - ACS Publications
In this work we present the successful application of functionalizing Pt nanoparticles (NPs)
with hydrophilic organic ligands as a strategy for enhancing their catalytic activity and …
with hydrophilic organic ligands as a strategy for enhancing their catalytic activity and …
Analyzing the surface of functional nanomaterials—how to quantify the total and derivatizable number of functional groups and ligands
D Geißler, N Nirmalananthan-Budau, L Scholtz… - Microchimica Acta, 2021 - Springer
Functional nanomaterials (NM) of different size, shape, chemical composition, and surface
chemistry are of increasing relevance for many key technologies of the twenty-first century …
chemistry are of increasing relevance for many key technologies of the twenty-first century …
Controlled metal nanostructures: Fertile ground for coordination chemists
Composition (metal or metal oxide core and organic coating), size, shape and structure are
the main parameters governing the properties of nano-objects. Driven by their huge …
the main parameters governing the properties of nano-objects. Driven by their huge …
Surface chemistry of “unprotected” nanoparticles: a spectroscopic investigation on colloidal particles
I Schrader, J Warneke, S Neumann… - The Journal of …, 2015 - ACS Publications
The preparation of colloidal nanoparticles in alkaline ethylene glycol is a powerful approach
for the preparation of model catalysts and ligand-functionalized nanoparticles. For these …
for the preparation of model catalysts and ligand-functionalized nanoparticles. For these …
Surface Molecule Manipulated Pt/TiO2 Catalysts for Selective Hydrogenation of Cinnamaldehyde
R Tao, BQ Shan, HD Sun, M Ding, QS Xue… - The Journal of …, 2021 - ACS Publications
Surface states—the electronic states arising as a result of the different bonding environment—
are easily contaminated by adsorbed molecules at nanoscale interfaces of metal …
are easily contaminated by adsorbed molecules at nanoscale interfaces of metal …
Asymmetric heterogeneous catalysis: transfer of molecular principles to nanoparticles by ligand functionalization
I Schrader, S Neumann, A Šulce, F Schmidt… - ACS …, 2017 - ACS Publications
We demonstrate the functionalization of supported nanoparticles (NPs) with ligands as an
approach to bridge the gap between homogeneous and heterogeneous catalysis. The use …
approach to bridge the gap between homogeneous and heterogeneous catalysis. The use …