Phonon Raman spectroscopy of nanocrystalline multinary chalcogenides as a probe of complex lattice structures

V Dzhagan, AP Litvinchuk, MY Valakh… - Journal of Physics …, 2022 - iopscience.iop.org
Abstract Ternary (I–III–VI) and quaternary (I–II–IV–VI) metal-chalcogenides like CuInS 2 or
Cu 2 ZnSn (S, Se) 4 are among the materials currently most intensively investigated for …

Low‐Temperature, Universal Synthetic Route for Mesoporous Metal Oxides by Exploiting Synergistic Effect of Thermal Activation and Plasma

KW Kim, H Seok, S Son, SJ Park, C Yang… - Advanced …, 2024 - Wiley Online Library
Mesoporous metal oxides exhibit excellent physicochemical properties and are widely used
in various fields, including energy storage/conversion, catalysis, and sensors. Although …

Control of secondary phases and disorder degree in Cu2ZnSnS4 films by sulfurization at varied subatmospheric pressures

IS Babichuk, MO Semenenko, S Golovynskyi… - Solar Energy Materials …, 2019 - Elsevier
Abstract Cu 2 ZnSnS 4 (CZTS) thin films deposited using direct current magnetron sputtering
and sulfurized at different argon atmosphere pressures of 950, 460 and 50 mbar are studied …

Synthesis and Characterization of Cu2ZnSnS4 Thin Films Obtained by Combined Magnetron Sputtering and Pulsed Laser Deposition

MY Zaki, F Sava, AT Buruiana, ID Simandan… - Nanomaterials, 2021 - mdpi.com
Cu2ZnSnS4 (CZTS) is a complex quaternary material, and obtaining a single-phase CZTS
with no secondary phases is known to be challenging and dependent on the production …

Raman and X-ray Photoemission Identification of Colloidal Metal Sulfides as Potential Secondary Phases in Nanocrystalline Cu2ZnSnS4 Photovoltaic Absorbers

O Selyshchev, Y Havryliuk, MY Valakh… - ACS Applied Nano …, 2020 - ACS Publications
The aim of this study is to establish reliable spectroscopic fingerprints of compounds that
may form as secondary phases in Cu2ZnSnS4 (CZTS) nanocrystals (NCs) synthesized by …

Raman map** of MoS2 at Cu2ZnSnS4/Mo interface in thin film

IS Babichuk, MO Semenenko, R Caballero… - Solar Energy, 2020 - Elsevier
Abstract A Cu 2 ZnSnS 4 (CZTS) thin film deposited on Mo contact film using direct current
magnetron sputtering and sulfurized is studied. The morphological and structural …

Phonon spectra of strongly luminescent nonstoichiometric Ag–In–S, Cu–In–S, and Hg–In–S nanocrystals of small size

V Dzhagan, O Selyshchev, O Raievska… - The Journal of …, 2020 - ACS Publications
We present a detailed analysis of Raman and infrared (IR) phonon spectra of strongly
luminescent nonstoichiometric M–In–S (M= Cu, Ag, Hg) and core/shell M–In-S/ZnS …

Investigation on Cu2MgSnS4 thin film prepared by spray pyrolysis for photovoltaic and humidity sensor applications

A Hammoud, A Jrad, B Yahmadi, M Souli, F Kouki… - Optical Materials, 2022 - Elsevier
In the present work, Cu 2 MgSnS 4 (CMTS) films are deposited by spray pyrolysis technique.
The impact of magnesium concentration during the synthesis of CMTS films is studied …

Spectroscopy and Theoretical Modeling of Phonon Vibration Modes and Band Gap Energy of Cu2ZnSn(SxSe1–x)4 Bulk Crystals and Thin Films

IS Babichuk, YA Romaniuk, S Golovynskyi… - ACS …, 2021 - ACS Publications
Semiconductor Cu2ZnSn (S x Se1–x) 4 (CZTSSe) solid solution is considered as a
perspective absorber material for solar cells. However, during its synthesis or deposition …

Influence of hydrogen plasma treatment on secondary phases in CZTS thin films for energy harvesting

IS Babichuk, MO Semenenko, R Caballero… - Materials Today …, 2021 - Elsevier
Abstract Cu 2 ZnSnS 4 (CZTS) thin films deposited using direct current magnetron sputtering
and sulfurized at argon atmosphere pressures of 950, 460, and 50 mbar are studied in a …