Glassy inorganic-organic hybrid materials for photonic applications

B Zhou, D Yan - Matter, 2024 - cell.com
Glass is an integral part of the amorphous materials family that has shown great potential in
applications ranging from daily life to high-tech fields such as healthcare, architecture …

Thermal Stability and Photostability of Highly Confined Molecular Nanocomposites

CY Chen, H Wang, A Arabi Shamsabadi… - The Journal of …, 2024 - ACS Publications
Capillary rise infiltration of molecular glasses into self-assembled layers of rigid
nanoparticles (NPs) can produce highly confined molecular nanocomposite films (MNCFs) …

Conflicting effects of extreme nanoconfinement on the translational and segmental motion of entangled polymers

RB Venkatesh, D Lee - Macromolecules, 2022 - ACS Publications
Physically confining polymers into nanoscale pores induces significant changes in their
dynamics. Although different results on the effect of confinement on the dynamics of …

Modeling the structure and relaxation in glycerol-silica nanocomposites

K Karakus, VV Ginzburg, K Promislow, L Rakesh - Soft Matter, 2025 - pubs.rsc.org
The relationship between the dynamics and structure of amorphous thin films and
nanocomposites near their glass transition is an important problem in soft-matter physics …

Effect of nanoscale confinement on polymer-infiltrated scaffold metal composites

SM Maguire, CR Bilchak, JS Corsi… - … Applied Materials & …, 2021 - ACS Publications
Most research on polymer composites has focused on adding discrete inorganic nanofillers
to a polymer matrix to impart properties not found in polymers alone. However, properties …

Probing Glass Transition Temperature of Polymer Thin Films under Static Shear Stress

DH Kim, CY Chen, Z Fakhraai - Macromolecules, 2024 - ACS Publications
Accurate characterization of the glass transition temperature (T g) in polymer thin films is
pivotal for their application in nanotechnology. Here, we introduced a novel and simple …

Two-stage photodegradation of indomethacin molecular nanocomposites under extreme confinement

CY Chen, H Wang, AA Shamsabadi, Z Fakhraai - Soft Matter, 2025 - pubs.rsc.org
The incorporation of a glassy material into a self-assembled nanoparticle (NP) film can
produce highly loaded nanocomposites. Reduction of the NP diameter can lead to extreme …

Effect of the surface polarity, through employing nonpolar spacer groups, on the glass-transition dynamics of poly (phenyl methylsiloxane) confined in alumina …

R Winkler, W Tu, M Dulski, L Laskowski… - …, 2021 - ACS Publications
Broadband dielectric spectroscopy and differential scanning calorimetry were used to study
the effect of changes in the surface conditions on the segmental dynamics of poly …

Polymer solution structure and dynamics within pores of hexagonally close-packed nanoparticles

CM Heil, A Jayaraman - Soft Matter, 2022 - pubs.rsc.org
Using coarse-grained molecular dynamics simulations, we examine structure and dynamics
of polymer solutions under confinement within the pores of a hexagonally close-packed …

Glass Transition Dynamics of Poly (phenylmethylsiloxane) Confined within Alumina Nanopores with Different Atomic Layer Deposition (ALD) Coatings

R Winkler, K Chat, AB Unni, M Dulski… - …, 2022 - ACS Publications
Dielectric spectroscopy (DS) and differential scanning calorimetry (DSC) were employed to
study the effect of changes in the surface conditions on the segmental dynamics of poly …