Nitrogen containing compounds are of great importance because of their interesting and
diverse biological activities. The construction of the C–N bond is of significant importance as …

Reactive intermediates as recognized chemical entities date back for over a century, and
among the earliest examples were simple free radicals, as identified in 1879, when it was …

The urea functionality is inherent to numerous bioactive compounds, including a variety of
clinically approved therapies. Urea containing compounds are increasingly used in …

Hypervalent iodine λ3‐benziodoxoles are common electrophilic transfer reagents known for
their enhanced stability compared to their non‐cyclic analogues. Herein we present data …

A copper‐catalyzed atroposelective ring‐opening reaction of cyclic diaryliodoniums, sodium
cyanate (NaOCN) and phenols is reported. The reaction chemoselectively affords axially …

A very practical method for the synthesis of unsymmetrical carbamide derivatives in good to
excellent yield was presented, without the need for any catalyst and at room temperature …

The first example of a regioselective β-arylation of benzo [b] thiophenes and thiophenes at
room temperature with aryl iodides as coupling partners is reported. This methodology …

Transition‐metal‐catalyzed enantioselective addition of aryl organometallic reagents to
imines has emerged as one of the most powerful tools for the formation of optically active …

A series of thirty‐three N, N′‐diaryl, dialkyl, and alkyl‐aryl ureas have been prepared in
pyridine or toluene by reaction of silylamines with CO2. This protocol is shown to provide …

The first example of near-room-temperature α-arylation of benzo [b] thiophenes is reported.
The discovery rests on the observation of a switch in α-/β-regioselectivity at different …