Organic synthesis using nitroxides
Nitroxides, also known as nitroxyl radicals, are long-lived or stable radicals with the general
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …
Photochemical and electrochemical applications of proton-coupled electron transfer in organic synthesis
We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …
Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts
In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …
reactions are widely performed during single and multistep synthesis. However, besides the …
Recent advances in radical C–H activation/radical cross-coupling
Research and industrial interest in radical C–H activation/radical cross-coupling chemistry
has continuously grown over the past few decades. These reactions offer fascinating and …
has continuously grown over the past few decades. These reactions offer fascinating and …
Catalysis of radical reactions: a radical chemistry perspective
The area of catalysis of radical reactions has recently flourished. Various reaction conditions
have been discovered and explained in terms of catalytic cycles. These cycles rarely stand …
have been discovered and explained in terms of catalytic cycles. These cycles rarely stand …
Iron catalysis in organic synthesis
I Bauer, HJ Knölker - Chemical reviews, 2015 - ACS Publications
The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …
June 2014 and represents a comprehensive update of a previous article published by Bolm …
Recent advances in the synthesis of nitrogen heterocycles via radical cascade reactions using isonitriles as radical acceptors
B Zhang, A Studer - Chemical Society Reviews, 2015 - pubs.rsc.org
Nitrogen heterocycles belong to a highly important class of compounds which are found in
various natural products, biologically active structures, and medicinally relevant compounds …
various natural products, biologically active structures, and medicinally relevant compounds …
Radical cascade cyclization of 1, n-enynes and diynes for the synthesis of carbocycles and heterocycles
J Xuan, A Studer - Chemical Society Reviews, 2017 - pubs.rsc.org
Carbo-and heterocycles are widely found in natural products, biologically active structures,
medicinally relevant compounds, and in many other fine chemicals. The development of …
medicinally relevant compounds, and in many other fine chemicals. The development of …
The electron is a catalyst
The electron is an efficient catalyst for conducting various types of radical cascade reaction
that proceed by way of radical and radical ion intermediates. But because electrons are …
that proceed by way of radical and radical ion intermediates. But because electrons are …
To each his own: isonitriles for all flavors. Functionalized isocyanides as valuable tools in organic synthesis
M Giustiniano, A Basso, V Mercalli… - Chemical Society …, 2017 - pubs.rsc.org
The term functionalized isocyanides refers to all those isocyanides in which a neighbouring
functional group can finely tune the reactivity of the isocyano group or can be exploited in …
functional group can finely tune the reactivity of the isocyano group or can be exploited in …