Open-shell radicals are usually thermodynamically and kinetically unstable due to their
incompletely satisfied valency. However, the rapid development of radical chemistry in the …

Conspectus Aromaticity is one of the most important concepts in organic chemistry to
understand the electronic properties of cyclic π-conjugated molecules. Over a century …

In this Feature Article, we highlight our recent efforts toward stable open-shell singlet
diradicaloids and polyradicaloids. A brief review on the historical works in the area is …

Heterocyclic diradicaloids with atom‐precise control over open‐shell nature are promising
materials for organic electronics and spintronics. Herein, we disclose quinoidal π‐extension …

Unpaired electrons of organic radicals can offer high electrical conductivity without do**,
but they typically suffer from low stability. Herein, we report two organic diradicaloids based …

The Suzuki–Miyaura cross-coupling between polyfluorinated arylboron nucleophiles and
aryl halides enables the efficient construction of polyfluorinated structural motifs frequently …

Unlike the conventional model of transition metal catalysis, ligands in metal–ligand
cooperative (or bifunctional) catalysis are involved in the substrate activations. Such …

Singlet fission offers the potential to overcome thermodynamic limits in solar cells by
converting the energy of a single absorbed photon into two distinct triplet excitons. However …

Molecular switches have received major attention to enable the reversible modulation of
various molecular properties and have been extensively used as trigger elements in diverse …

1. INTRODUCTION Organometallic catalysis takes advantage of the ability to introduce
highly distinctive reactivity of the corresponding metal complexes by modifying the ligand …