Aromatic Endoperoxides

EL Clennan - Photochemistry and Photobiology, 2023 - Wiley Online Library
The fundamental aspects of aromatic endoperoxide chemistry are reviewed including their
synthesis and reactions. The discussion will focus on factors that will both enhance and …

Application of Discrete First‐Row Transition‐Metal Complexes as Photosensitisers

K Behm, RD McIntosh - ChemPlusChem, 2020 - Wiley Online Library
This Minireview summarises and critically evaluates recent advances in the utilisation of
discrete first‐row transition‐metal (TM) complexes as photosensitisers. Whilst many …

Self-Sensitized and Reversible O2 Reactivity with Bisphenalenyls for Simple, Tunable, and Multicycle Colorimetric Oxygen-Sensing Films

M Imran, MS Chen - ACS Applied Materials & Interfaces, 2021 - ACS Publications
Monitoring the levels of molecular oxygen (O2) is critical for numerous applications, but
there is still a long-standing challenge to develop robust and cost-effective colorimetric …

Stationary concentration of 1O2 over 1O2 quantum yield: Next level of photoactivity analysis

SM Korobkov, KP Birin, AY Tsivadze - Dyes and Pigments, 2023 - Elsevier
The investigation of the activity of photosensitizers is a multivariate challenge for their further
application in photocatalysis. Porphyrins are attractive photoactive molecules for chemical …

Potentiation effect of iodine species on the antimicrobial capability of surfaces coated with electroactive phthalocyanines

E Baigorria, JE Durantini, SR Martínez… - ACS Applied Bio …, 2021 - ACS Publications
The spreading of different infections can occur through direct contact with glass surfaces in
commonly used areas. Incorporating the use of alternative therapies in these materials …

Indirect photodegradation of sulfamethoxazole and trimethoprim by hydroxyl radicals in aquatic environment: mechanisms, transformation products and eco-toxicity …

J Yang, G Lv, C Zhang, Z Wang, X Sun - International Journal of …, 2020 - mdpi.com
The bacteriostatic antibiotics, sulfamethoxazole (SMX) and trimethoprim (TMP), have
frequently been found in wastewater and surface water, which raises the concerns about …

Interparticle delivery and detection of volatile singlet oxygen at air/solid interfaces

AM Durantini, A Greer - Environmental Science & Technology, 2021 - ACS Publications
An interparticle system has been devised, allowing airborne singlet oxygen to transfer
between particle surfaces. Singlet oxygen is photogenerated on a sensitizer particle, where …

Indirect photodegradation of fludioxonil by hydroxyl radical and singlet oxygen in aquatic environment: Mechanism, photoproducts formation and eco-toxicity …

J Yang, Z Wang, G Lv, W Liu, Y Wang, X Sun… - … and Environmental Safety, 2020 - Elsevier
Fludioxonil has been proven valuable as a broad-spectrum fungicide. However, there are
concerns about its risk posed to non-target organisms in aquatic environments. In this paper …

Chemically triggered release of singlet oxygen from bisphenalenyl endoperoxides with a brønsted acid

M Imran, MS Chen - Organic Letters, 2022 - ACS Publications
Aromatic endoperoxides have emerged as intriguing stimulus-responsive materials for
molecular oxygen (O2) storage and delivery but are currently limited in their application …

Stepwise versus Concerted: Theoretical Insights into the Stereoselectivity in Aryl Imine Formation Assisted by Acid and Water

X Ren, K Liu, Y Lu, W Ding, S Lei… - The Journal of Physical …, 2023 - ACS Publications
The wide applications of the aryl Schiff base require extensive understanding of the
mechanism of its formation, which remains unclear. In this work, the detailed formation …