Monovalent group 15 cations L2Pn+(L= σ-donor ligands, Pn= N, P, As, Sb, Bi) have attracted
significant experimental and theoretical interest because of their unusual electronic …

Carbenes and their analogues have constantly enthralled chemists with their intriguing
reactivity of ambiphilic character stemming from their electronic structures. Phosphenium …

The kinetically stabilized group 14 cations [RindEMe2][B (C6F5) 4](E= Si, Sn, Pb) were
prepared and fully characterized (Rind= dispiro [fluorene-9, 3′-(1′, 1′, 7′, 7 …

Phosphenium ions [R2P]+ are important and highly reactive dicoordinate phosphorus
species. Herein, we report a rearrangement of the carbocation into the phosphenium cation …

Phosphenium ions are highly reactive species with the formula of RR 'P+. Although
phosphenium ions were proposed as the invaluable intermediates of various important …

Do** polycyclic aromatic hydrocarbons with heteroatoms enables manipulation of their
electronic structures. Herein, the structures and properties of phosphorus (P) doped …

Arsenic‐bridged silafluorene and germafluorene were synthesized as a novel class of mixed‐
heteroatom‐bridged heterofluorenes. Their structures, photophysical properties, and …

Fluorenyl cations are textbook examples of 4π electron antiaromatic five‐membered ring
systems. So far, they were reported only as short‐lived intermediates generated under …

The newly prepared and fully characterized stibenium and bismuthenium ions
[RindMesE]+(E= Sb, Bi; Rind= dispiro [fluorene‐9, 3′‐(1′, 1′, 7′, 7′‐tetramethyl‐s …

A bis (ferrocenyl) phosphenium ion with intramolecular phosphine‐coordination,
incorporated within [2] ferrocenophane framework, was synthesized as an air‐stable …