Atropisomerism is a stereochemical behavior portrayed by three-dimensional molecules that
bear rotationally restricted σ bond. Akin to the well-represented point-chiral molecules …

Enantiomers, where chirality arises from restricted rotation around a single bond, are
atropisomers. Due to the unique nature of the origins of their chirality, synthetic strategies to …

With the rapid development of asymmetric catalysis, the demand for the enantioselective
synthesis of complex and diverse molecules with different chiral elements is increasing …

The first catalytic asymmetric construction of 3, 3′‐bisindole skeletons bearing both axial
and central chirality has been established by organocatalytic asymmetric addition reactions …

This review explores the fascinating world of molecules featuring multiple stereogenic
elements, unraveling the different strategies designed over the years for their …

The axially chiral indole-aryl motifs are present in natural products and biologically active
compounds as well as in chiral ligands. Atroposelective indole formation is an efficient …

Difunctionalization of olefins offers an attractive approach to access complex chiral
structures. Reported herein is the design of N-protected O-allylhydroxyamines as …

As has been well-recognized, semipinacol rearrangement functions as an exceptionally
useful methodology in the synthesis of β-functionalized ketones, creation of quaternary …

Electrophilic halogenation reactions have been a reliable approach to accessing
organohalides. During the past decades, various catalytic systems have been developed for …

A dirhodium (II)/phosphine catalyst with a chiral environment at the bridging site was
developed for the asymmetric arylation of phenanthrene-9, 10-diones with arylboronic acids …