Visible light-induced transition metal catalysis

KPS Cheung, S Sarkar, V Gevorgyan - Chemical reviews, 2021 - ACS Publications
In recent years, visible light-induced transition metal catalysis has emerged as a new
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …

Enantioselective radical reactions using chiral catalysts

S Mondal, F Dumur, D Gigmes, MP Sibi… - Chemical …, 2022 - ACS Publications
Benefiting from the impressive increase in fundamental knowledge, the last 20 years have
shown a continuous burst of new ideas and consequently a plethora of new catalytic …

[PDF][PDF] Photoinduced intermolecular hydrogen atom transfer reactions in organic synthesis

H Cao, X Tang, H Tang, Y Yuan, J Wu - Chem Catalysis, 2021 - cell.com
Hydrogen-atom transfer (HAT) provides straightforward methods to generate open-shell
radical intermediates from RH (R= C, Si, etc.) bonds and offers unique opportunities for …

Catalytic hydrogen atom transfer to alkenes: a roadmap for metal hydrides and radicals

SL Shevick, CV Wilson, S Kotesova, D Kim… - Chemical …, 2020 - pubs.rsc.org
Hydrogen atom transfer from a metal hydride (MHAT) has emerged as a powerful, if
puzzling, technique in chemical synthesis. In catalytic MHAT reactions, earth-abundant …

Recent Advances in Mn, Fe, Co, and Ni-Catalyzed Organic Reactions

LJ Li, Y He, Y Yang, J Guo, Z Lu, C Wang… - CCS …, 2024 - chinesechemsoc.org
This paper reviewed the recent research progress of organic reactions catalyzed by four
typical earth-abundant and 3d metal catalysts: Mn, Fe, Co, and Ni complexes and mainly …

A triple photoredox/cobalt/brønsted acid catalysis enabling markovnikov hydroalkoxylation of unactivated alkenes

M Nakagawa, Y Matsuki, K Nagao… - Journal of the American …, 2022 - ACS Publications
We demonstrate Markovnikov hydroalkoxylation of unactivated alkenes using alcohols
through a triple catalysis consisting of photoredox, cobalt, and Brønsted acid catalysts under …

Metalloradical approach for concurrent control in intermolecular radical allylic C− H amination

P Xu, J **e, DS Wang, XP Zhang - Nature chemistry, 2023 - nature.com
Although they offer great potentials, the high reactivity and diverse pathways of radical
chemistry pose difficult problems for applications in organic synthesis. In addition to the …

Direct excitation strategy for radical generation in organic synthesis

Y Sumida, H Ohmiya - Chemical Society Reviews, 2021 - pubs.rsc.org
Visible-light-mediated chemical processes have been vigorously studied and have led to
state-of-the-art synthetic chemistry since they enable the control of radical generation and …

Co-catalyzed hydrofluorination of alkenes: photocatalytic method development and electroanalytical mechanistic investigation

J Liu, J Rong, DP Wood, Y Wang… - Journal of the …, 2024 - ACS Publications
The hydrofluorination of alkenes represents an attractive strategy for the synthesis of
aliphatic fluorides. This approach provides a direct means to form C (sp3)–F bonds …

A dual light-driven palladium catalyst: Breaking the barriers in carbonylation reactions

GM Torres, Y Liu, BA Arndtsen - Science, 2020 - science.org
Transition metal–catalyzed coupling reactions have become one of the most important tools
in modern synthesis. However, an inherent limitation to these reactions is the need to …