Visible light-induced transition metal catalysis
In recent years, visible light-induced transition metal catalysis has emerged as a new
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …
Enantioselective radical reactions using chiral catalysts
Benefiting from the impressive increase in fundamental knowledge, the last 20 years have
shown a continuous burst of new ideas and consequently a plethora of new catalytic …
shown a continuous burst of new ideas and consequently a plethora of new catalytic …
[PDF][PDF] Photoinduced intermolecular hydrogen atom transfer reactions in organic synthesis
Hydrogen-atom transfer (HAT) provides straightforward methods to generate open-shell
radical intermediates from RH (R= C, Si, etc.) bonds and offers unique opportunities for …
radical intermediates from RH (R= C, Si, etc.) bonds and offers unique opportunities for …
Catalytic hydrogen atom transfer to alkenes: a roadmap for metal hydrides and radicals
SL Shevick, CV Wilson, S Kotesova, D Kim… - Chemical …, 2020 - pubs.rsc.org
Hydrogen atom transfer from a metal hydride (MHAT) has emerged as a powerful, if
puzzling, technique in chemical synthesis. In catalytic MHAT reactions, earth-abundant …
puzzling, technique in chemical synthesis. In catalytic MHAT reactions, earth-abundant …
Recent Advances in Mn, Fe, Co, and Ni-Catalyzed Organic Reactions
This paper reviewed the recent research progress of organic reactions catalyzed by four
typical earth-abundant and 3d metal catalysts: Mn, Fe, Co, and Ni complexes and mainly …
typical earth-abundant and 3d metal catalysts: Mn, Fe, Co, and Ni complexes and mainly …
A triple photoredox/cobalt/brønsted acid catalysis enabling markovnikov hydroalkoxylation of unactivated alkenes
M Nakagawa, Y Matsuki, K Nagao… - Journal of the American …, 2022 - ACS Publications
We demonstrate Markovnikov hydroalkoxylation of unactivated alkenes using alcohols
through a triple catalysis consisting of photoredox, cobalt, and Brønsted acid catalysts under …
through a triple catalysis consisting of photoredox, cobalt, and Brønsted acid catalysts under …
Metalloradical approach for concurrent control in intermolecular radical allylic C− H amination
Although they offer great potentials, the high reactivity and diverse pathways of radical
chemistry pose difficult problems for applications in organic synthesis. In addition to the …
chemistry pose difficult problems for applications in organic synthesis. In addition to the …
Direct excitation strategy for radical generation in organic synthesis
Y Sumida, H Ohmiya - Chemical Society Reviews, 2021 - pubs.rsc.org
Visible-light-mediated chemical processes have been vigorously studied and have led to
state-of-the-art synthetic chemistry since they enable the control of radical generation and …
state-of-the-art synthetic chemistry since they enable the control of radical generation and …
Co-catalyzed hydrofluorination of alkenes: photocatalytic method development and electroanalytical mechanistic investigation
The hydrofluorination of alkenes represents an attractive strategy for the synthesis of
aliphatic fluorides. This approach provides a direct means to form C (sp3)–F bonds …
aliphatic fluorides. This approach provides a direct means to form C (sp3)–F bonds …
A dual light-driven palladium catalyst: Breaking the barriers in carbonylation reactions
Transition metal–catalyzed coupling reactions have become one of the most important tools
in modern synthesis. However, an inherent limitation to these reactions is the need to …
in modern synthesis. However, an inherent limitation to these reactions is the need to …