A chelate like no other: exploring the synthesis, coordination chemistry and applications of imidoyl amidine frameworks

AA Kitos, N Mavragani, M Murugesu, JL Brusso - Materials Advances, 2020 - pubs.rsc.org
Since the remarkable work by Werner, the design and use of chelating ligands have played
an essential part in coordination chemistry. While ligands such as 2, 4-pentanedione (acac) …

Photo-and Electroluminescent Neutral Iridium (III) Complexes Bearing Imidoylamidinate Ligands

EA Katlenok, AV Rozhkov, RR Ramazanov… - Inorganic …, 2022 - ACS Publications
Imidoylamidinate-based heteroleptic bis (2-phenylbenzothiazole) iridium (III) and-rhodium
(III) complexes [(bt) 2M (N∩ N)](bt= 2-phenylbenzothiazole, N∩ N= N′-(benzo [d] thiazol-2 …

1, 2-Dihydro-1, 3, 2-diazaborinine tautomer as an electron-pair donor in hydrogen-bonded complexes

I Alkorta, J Elguero, JE Del Bene - Canadian Journal of …, 2021 - cdnsciencepub.com
Ab initio MP2/aug'-cc-pVTZ calculations have been carried out to investigate 1, 2-dihydro-1,
3, 2-diazaborinine: HX complexes for HX= H+, HF, HCl, H2O, HCN, NH3, HCP, and HCCH …

[PDF][PDF] Development and Mechanistic Analysis of Novel CO2 Reduction Electrocatalysts

ZS Dubrawski - Development, 2023 - prism.ucalgary.ca
The ever-growing anthropogenic concentrations of CO2 in our atmosphere has led to an
entire industry centered around Carbon Capture and Utilization (CCU). One central pillar of …

Ferromagnetically coupled dinuclear M II complexes based on a boratriazine ligand framework

JM Savard, G Brunet, A Srinivasan, M Murugesu… - Dalton …, 2018 - pubs.rsc.org
A boratriazine ligand, which incorporates attractive features from both bodipy and terpy, has
been used to synthesize [Fe2II (μ1, 1-N3) 2 (Py2F2BTA) 2 (N3) 2](1) and [Co2II (μ1, 1-N3) 2 …

Controlling the nuclearity and topology of cobalt complexes through hydration at the ppm level

R Castañeda, M Rouzieres, R Clérac… - Journal of Materials …, 2020 - pubs.rsc.org
Through ppm level control over the degree of hydration (eg, 300 ppm vs. 10 000 ppm), the
nuclearity and topology of cobalt complexes can be tailored, as demonstrated here. This …

Exploring the coordination chemistry of terpy-type boratriazine chelates through a series of mononuclear iron (III) complexes

JM Savard, R Castañeda, B Gabidullin, JL Brusso - Polyhedron, 2019 - Elsevier
We have begun to tap into the rich ligating potential of 2, 2-difluoro-4, 6-bis (2-pyridyl)-1, 3-
dihydro-1, 3, 5, 2-triazaborinine (Py 2 F 2 BTA) and 2, 2-difluoro-4, 6-bis (2-pyrimidinyl)-1, 3 …

Designing Molecular Materials Through Thiazyl-Based Radicals

N Yutronkie - 2020 - ruor.uottawa.ca
Neutral molecular radicals have received increasing attention as building blocks for
functional molecular materials owing to their intrinsic conductive and magnetic properties …

Rational Design of Tetranuclear Complexes Employing N‐Imidoylamidine Based Ligands

R Castañeda, KLM Harriman… - European Journal of …, 2019 - Wiley Online Library
Ligands such as N‐2‐pyrimidylimidoyl‐2‐pyrimidylamidine (Pm2ImAm) possess both a
bidentate and tridentate coordination site within a single ligand framework. Taking …