Nuclear quantum effects in water and aqueous systems: Experiment, theory, and current challenges
Nuclear quantum effects influence the structure and dynamics of hydrogen-bonded systems,
such as water, which impacts their observed properties with widely varying magnitudes. This …
such as water, which impacts their observed properties with widely varying magnitudes. This …
The structural origin of anomalous properties of liquid water
Water is unique in its number of unusual, often called anomalous, properties. When hot it is
a normal simple liquid; however, close to ambient temperatures properties, such as the …
a normal simple liquid; however, close to ambient temperatures properties, such as the …
The structure of interfacial water on gold electrodes studied by x-ray absorption spectroscopy
The molecular structure of the electrical double layer determines the chemistry in all
electrochemical processes. Using x-ray absorption spectroscopy (XAS), we probed the …
electrochemical processes. Using x-ray absorption spectroscopy (XAS), we probed the …
How to Assess and Predict Electrical Double Layer Properties. Implications for Electrocatalysis
The electrical double layer (EDL) plays a central role in electrochemical energy systems,
impacting charge transfer mechanisms and reaction rates. The fundamental importance of …
impacting charge transfer mechanisms and reaction rates. The fundamental importance of …
Water: A tale of two liquids
Water is the most abundant liquid on earth and also the substance with the largest number
of anomalies in its properties. It is a prerequisite for life and as such a most important subject …
of anomalies in its properties. It is a prerequisite for life and as such a most important subject …
Ultrahigh density of gas molecules confined in surface nanobubbles in ambient water
To understand the unexpected and puzzling long-term stability of nanoscale gas bubbles, it
is crucial to probe their nature and intrinsic properties. We report herein synchrotron-based …
is crucial to probe their nature and intrinsic properties. We report herein synchrotron-based …
Perspective on the structure of liquid water
We present a picture that combines discussions regarding the thermodynamic anomalies in
ambient and supercooled water with recent interpretations of X-ray spectroscopy and …
ambient and supercooled water with recent interpretations of X-ray spectroscopy and …
X-ray and electron spectroscopy of water
Here we present an overview of recent developments of X-ray and electron spectroscopy to
probe water at different temperatures. Photon-induced ionization followed by detection of …
probe water at different temperatures. Photon-induced ionization followed by detection of …
Soft x-ray absorption spectroscopy of liquids and solutions
JW Smith, RJ Saykally - Chemical reviews, 2017 - ACS Publications
X-ray absorption spectroscopy (XAS) is an electronic absorption technique for which the
initial state is a deeply buried core level. The photon energies corresponding to such …
initial state is a deeply buried core level. The photon energies corresponding to such …
Electrolytes induce long-range orientational order and free energy changes in the H-bond network of bulk water
Electrolytes interact with water in many ways: changing dipole orientation, inducing charge
transfer, and distorting the hydrogen-bond network in the bulk and at interfaces. Numerous …
transfer, and distorting the hydrogen-bond network in the bulk and at interfaces. Numerous …