The behavior of palladium acetate is reviewed with respect to its synthesis, characterization,
structure (in both solution and solid state), and activation pathways. In addition, comparisons …

Conspectus The design of solid-state materials whose properties and functions can be
manipulated in a controlled manner by the application of light is an important objective in …

This paper describes a new method for the catalytic aerobic oxygenation of unactivated sp3-
C–H bonds. This transformation utilizes Pd (OAc) 2 as a catalyst in conjunction with NaNO3 …

This feature article examines the potential of heterogeneous Pd species to mediate catalytic
C–H bond functionalisation processes employing suitable substrates (eg aromatic …

A regioselective anti-hydrochlorination of unactivated alkynes is reported. The reaction
utilizes in situ generated HCl as the source of both the Cl–and H+ and is catalyzed by …

The cycloisomerization of enynes catalyzed by Pd (OAc) 2 and bis-benzylidene
ethylenediamine (bbeda) is a landmark methodology in transition-metal-catalyzed …

Understanding complex reaction systems is critical in chemistry. While synthetic methods for
selective formation of products are sought after, oftentimes it is the full reaction signature, ie …

Commercially available palladium acetate often contains two major impurities, whose
presence can impact the overall catalytic efficacy. This systematic study provides a …

Increasing evidence indicates that silver salts can play a role in the C–H activation step of
palladium-catalyzed C–H functionalization. Here we isolate a silver (I) complex by C–H …

This Minireview highlights the redox and non‐innocent behavior of NOx ligands (x= 1, 2, or
3) in selected Pd‐mediated processes, for example, alkene and aromatic oxidation …