Choosing between Ti (ii) and Ti (iii): selective reduction of titanocene dichloride by elemental lanthanides

G Bousrez, D Harakat, S Chevreux… - Dalton …, 2024 - pubs.rsc.org
The reduction of titanocene dichloride Cp2TiCl2 with lanthanide metals has led to the
discovery of a surprising lanthanide effect: while with most lanthanides, a divalent [Cp2Ti] …

Titanium‐Catalyzed Reaction of Silacyclobutanes with Alkenes: Mimicking the Reactivity and Reversing the Selectivity Towards Late Transition Metals

Y Wang, J Zhang, F Wang, L Wu - Angewandte Chemie - Wiley Online Library
Transition metal‐catalyzed ring opening and expansion reactions of silacyclobutanes
(SCBs) constitute an atom‐and step‐economical strategy to construct value‐added silicon …