Super atomic clusters: design rules and potential for building blocks of materials

P Jena, Q Sun - Chemical reviews, 2018 - ACS Publications
Atomic clusters, consisting of a few to a few thousand atoms, have emerged over the past 40
years as the ultimate nanoparticles, whose structure and properties can be controlled one …

Endohedrally doped cage clusters

J Zhao, Q Du, S Zhou, V Kumar - Chemical Reviews, 2020 - ACS Publications
The discovery of carbon fullerene cages and their solids opened a new avenue to build
materials from stable cage clusters as “artificial atoms” or “superatoms” instead of atoms …

Rh19: A high-spin super-octahedron cluster

Y Jia, CQ Xu, C Cui, L Geng, H Zhang, YY Zhang… - Science …, 2023 - science.org
Probing atomic clusters with magic numbers is of supreme importance but challenging in
cluster science. Pronounced stability of a metal cluster often arises from coincident …

A review of state of the art in phosphine ligated gold clusters and application in catalysis

RH Adnan, JML Madridejos, AS Alotabi… - Advanced …, 2022 - Wiley Online Library
Atomically precise gold clusters are highly desirable due to their well‐defined structure
which allows the study of structure–property relationships. In addition, they have potential in …

Special and general superatoms

Z Luo, AW Castleman - Accounts of chemical research, 2014 - ACS Publications
Conspectus Bridging the gap between atoms and macroscopic matter, clusters continue to
be a subject of increasing research interest. Among the realm of cluster investigations, an …

Superatoms: electronic and geometric effects on reactivity

AC Reber, SN Khanna - Accounts of Chemical Research, 2017 - ACS Publications
Conspectus The relative role of electronic and geometric effects on the stability of clusters
has been a contentious topic for quite some time, with the focus on electronic structure …

[HTML][HTML] Structural and electronic properties of medium-sized beryllium doped magnesium BeMgn clusters and their anions

Y Zhao, Y Xu, P Chen, Y Yuan, Y Qian, Q Li - Results in physics, 2021 - Elsevier
Bimetallic clusters have attracted much attention because of the structural and property
changes that occur: cluster size and do**. Here, we performed a structural search of the …

Probing the effects of lithium do** on structures, properties, and stabilities of magnesium cluster anions

XY Zhang, YR Zhao, HX Li, KG Cheng, ZR Liu… - Chinese …, 2023 - iopscience.iop.org
Probing the effects of lithium do** on structures, properties, and stabilities of magnesium
cluster anions - IOPscience Skip to content IOP Science home Accessibility Help Search …

Probing the structural evolution, electronic and vibrational properties of anionic sodium-doped magnesium clusters

HX Li, KG Cheng, JC Wang, ZP Liu, H He… - Computational Materials …, 2023 - Elsevier
Bimetallic clusters aroused a great deal of attention in materials science because of their
novel properties, depending sensitively on their size, structure, and composition. Herein, we …

Main Group Metal–Actinide Magnetic Coupling and Structural Response Upon U4+ Inclusion Into Bi, Tl/Bi, or Pb/Bi Cages

N Lichtenberger, RJ Wilson… - Journal of the …, 2016 - ACS Publications
The encapsulation of actinide ions in intermetalloid clusters has long been proposed but
was never realized synthetically. We report the isolation and experimental, as well as …