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Transition‐Metal‐Mediated and‐Catalyzed C− F Bond Activation by Fluorine Elimination
The activation of carbon–fluorine (C− F) bonds is an important topic in synthetic organic
chemistry. Metal‐mediated and‐catalyzed elimination of β‐or α‐fluorine proceeds under …
chemistry. Metal‐mediated and‐catalyzed elimination of β‐or α‐fluorine proceeds under …
Functionalization of fluorinated molecules by transition-metal-mediated C–F bond activation to access fluorinated building blocks
T Ahrens, J Kohlmann, M Ahrens, T Braun - Chemical Reviews, 2015 - ACS Publications
Fluorinated organic compounds increasingly gain importance in numerous areas of
chemistry and everyday life. Building blocks which contain fluorinated entities are of high …
chemistry and everyday life. Building blocks which contain fluorinated entities are of high …
CF bond activation under transition-metal-free conditions
The unique properties of fluorine-containing organic compounds make fluorine substitution
attractive for the development of pharmaceuticals and various specialty materials, which …
attractive for the development of pharmaceuticals and various specialty materials, which …
Titanium catalysis for the synthesis of fine chemicals–development and trends
Titanium is the second most abundant transition metal and is already a key player in
important industrial processes (eg polyethylene). Titanium is an attractive metal to use for …
important industrial processes (eg polyethylene). Titanium is an attractive metal to use for …
Fluorocarbon refrigerants and their syntheses: Past to present
AJ Sicard, RT Baker - Chemical Reviews, 2020 - ACS Publications
This Review chronicles the progress made in the field of small fluorocarbon synthesis since
their invention in the early 1930s by Thomas Midgley, Jr., and his coworkers, with special …
their invention in the early 1930s by Thomas Midgley, Jr., and his coworkers, with special …
Synthesis of fluorinated building blocks by transition‐metal‐mediated hydrodefluorination reactions
The activation and functionalization of carbon–fluorine bonds can be considered as a major
challenge in organometallic chemistry. The growing demand for means to introduce fluorine …
challenge in organometallic chemistry. The growing demand for means to introduce fluorine …
Fluorine and gold: A fruitful partnership
Gold-catalyzed reactions have witnessed an exponential growth in the past decade. When
the unique modes of activation exhibited by gold species meet species with either …
the unique modes of activation exhibited by gold species meet species with either …
Rhodium-catalyzed asymmetric arylation/defluorination of 1-(trifluoromethyl) alkenes forming enantioenriched 1, 1-difluoroalkenes
Y Huang, T Hayashi - Journal of the American Chemical Society, 2016 - ACS Publications
The reaction of 1-(trifluoromethyl) alkenes (CF3CH= CHR) with arylboroxines (ArBO) 3 in the
presence of a chiral diene-rhodium catalyst gave high yields of chiral 1, 1-difluoroalkenes …
presence of a chiral diene-rhodium catalyst gave high yields of chiral 1, 1-difluoroalkenes …
Stereoselective Synthesis of Z Fluoroalkenes through Copper‐Catalyzed Hydrodefluorination of gem‐Difluoroalkenes with Water
J Hu, X Han, Y Yuan, Z Shi - Angewandte Chemie International …, 2017 - Wiley Online Library
A copper catalytic system was established for the stereoselective hydrodefluorination of gem‐
difluoroalkenes through C− F activation to synthesize various Z fluoroalkenes. H2O is used …
difluoroalkenes through C− F activation to synthesize various Z fluoroalkenes. H2O is used …
Cleavage of C(sp3)–F Bonds in Trifluoromethylarenes Using a Bis(NHC)nickel(0) Complex
The first example of the oxidative addition of a C (sp3)–F bond in trifluoromethylarenes to a
nickel (0) complex is described. A nickel (0) complex that bears two N-heterocyclic carbene …
nickel (0) complex is described. A nickel (0) complex that bears two N-heterocyclic carbene …