Catalysis offers a straightforward route to prepare various value-added molecules starting
from readily available raw materials. The catalytic reactions mostly involve multi-electron …

Chemistry of Schiff base (SB) ligands began in 1864 due to the discovery made by Hugo
Schiff (Schiff, H., Justus Liebigs Ann. der Chemie 1864, 131 (1), 118–119). However, there is …

Herein we disclose a series of phosphine-free cobalt (II)-based catalytic systems bearing a
redox non-innocent amine functionalized azo-aromatic pincer-like ligand for the synthesis of …

Abstract N= C–C= N backbone ligands have been extensively studied for s-, p-, d-and f-
block elements over the last several decades. Their diverse bonding modes and redox …

In this report, a new imidazole-and amide-functionalized pincer-like Cu (II) complex (1) was
synthesized and characterized. By employing 1 and 9-azabicyclo [3.3. 1] nonane NH-Oxyl …

5, 7, 12, 14-Tetraazapentacene-6, 13-quinone (L) reacts with 2 equiv of [Ru (acac) 2
(CH3CN) 2] to form two linkage isomeric bis (chelate) compounds,[{RuII (acac) 2} 2 (μ-L)] …

An unprecedented reactivity profile of biochemically relevant R‐benzofuroxan (R= H, Me,
Cl), with high structural diversity and molecular complexity on a selective {Ru (acac) …

Pyrazolone derived Ru (III) complexes were synthesized and comprehensively
characterized by spectral techniques. The true nature of the complexes was revealed by X …

(Methylthio) aniline (H2L1) and 2‐(phenylthio) aniline (H2L2) were treated with n‐
butyllithium to yield the corresponding anilides [LiHL1] and [LiHL2]. Recrystallization from …

Three chemical reactions of two 2-aminothioethers and 2-aminothiophenol with CpRuIICl
(PPh3) 2 (Cp–= cyclopentadienyl anion), under identical reaction conditions, are reported …