Optical phenomena in molecule-based magnetic materials

JJ Zakrzewski, M Liberka, J Wang, S Chorazy… - Chemical …, 2024 - ACS Publications
Since the last century, we have witnessed the development of molecular magnetism which
deals with magnetic materials based on molecular species, ie, organic radicals and metal …

Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

Dehydration–Hydration Switching of Single-Molecule Magnet Behavior and Visible Photoluminescence in a Cyanido-Bridged DyIIICoIII Framework

Y **n, J Wang, M Zychowicz… - Journal of the …, 2019 - ACS Publications
Microporous magnets compose a class of multifunctional molecule-based materials where
desolvation-driven structural transformation leads to the switching of magnetic properties …

Recent progress on cyano-bridged transition-metal-based single-molecule magnets and single-chain magnets

JH Wang, ZY Li, M Yamashita, XH Bu - Coordination Chemistry Reviews, 2021 - Elsevier
Novel functional molecular-based magnetic materials, especially some members of the
Prussian blue family, have gained significant attention over the past few decades as they …

Recent progress in transition metal hexacyanometallates: From structure to properties and functionality

Y Avila, P Acevedo-Pena, L Reguera… - Coordination Chemistry …, 2022 - Elsevier
The coordination chemistry of transition metal hexacyanometallates is a field of continuous
advances and emerging applications. In the last three decades, relevant progress has been …

What controls the sign and magnitude of magnetic anisotropy in tetrahedral cobalt (II) single-ion magnets?

S Vaidya, S Tewary, SK Singh, SK Langley… - Inorganic …, 2016 - ACS Publications
A family of mononuclear tetrahedral cobalt (II) thiourea complexes,[Co (L1) 4](NO3) 2 (1)
and [Co (L x) 4](ClO4) 2 where x= 2 (2), 3 (3), 4 (4)(where L1= thiourea, L2= 1, 3 …

Single‐chain magnet based on cobalt (II) thiocyanate as XXZ spin chain

M Rams, A Jochim, M Böhme… - … A European Journal, 2020 - Wiley Online Library
The cobalt (II) in [Co (NCS) 2 (4‐methoxypyridine) 2] n are linked by pairs of thiocyanate
anions into linear chains. In contrast to a previous structure determination, two …

Magneto-Structural Correlations in Pseudotetrahedral Forms of the [Co(SPh)4]2– Complex Probed by Magnetometry, MCD Spectroscopy, Advanced EPR …

EA Suturina, J Nehrkorn, JM Zadrozny, J Liu… - Inorganic …, 2017 - ACS Publications
The magnetic properties of pseudotetrahedral Co (II) complexes spawned intense interest
after (PPh4) 2 [Co (SPh) 4] was shown to be the first mononuclear transition-metal complex …

Coordination clusters of 3d-metals that behave as single-molecule magnets (SMMs): synthetic routes and strategies

D Maniaki, E Pilichos, SP Perlepes - Frontiers in Chemistry, 2018 - frontiersin.org
The area of 3d-metal coordination clusters that behave as Single-Molecule Magnets (SMMs)
is now quite mature within the interdisciplinary field of Molecular Magnetism. This area has …

Magnetic Slow Relaxation in a Metal–Organic Framework Made of Chains of Ferromagnetically Coupled Single‐Molecule Magnets

G Huang, G Fernandez‐Garcia… - … A European Journal, 2018 - Wiley Online Library
We report the study of a Dy‐based metal–organic framework (MOF) with unprecedented
magnetic properties. The compound is made of nine‐coordinated DyIII magnetic building …