The stereochemistry in the conversion of (E)-α, β-unsaturated esters into the corresponding
β, γ-unsaturated esters, and that in the conversion of aldehydes into the silyl enol ethers …

The sequential 1, 4-elimination reaction of (E)-4-alkoxy-2-butenyl benzoates and [1, 2]-Wittig
rearrangement gave (2 Z, 4 E)-2, 4-pentadien-1-ols stereoselectively. Z-Selective formation …

An efficient two‐step synthetic approach of benzo [a] carbazoles from 2‐arylindoles has
been developed. The first step is a propargylation of 2‐arylindoles at the 3‐position …

“Syn–effect” has been recognized as a major cause of stabilizing the syn–conformation at
the transition state of a number of reactions against the steric hindrance. This account deals …

The successive treatment of (E)-δ-(arylmethoxy)-substituted allylic sulfones with t-BuOK and
LDA afforded the corresponding (Z)-2, 4-dienyl alcohols with high stereoselectivities via 1, 4 …

Vinylic phenylsulfones containing a β-hydroxyl stereocenter undergo a diastereoselective
isomerization to the corresponding allylic isomer upon treatment with 1, 8-diazabicyclo (5.4 …

The stereochemistry of nucleophilic addition of amines to (E)-1-tosyl-1, 3-butadiene was
investigated. The Z/E ratios of the resulting allylic sulfones varied with amines, solvents …

The stereochemistry of the elimination reaction of acyclic (E)-allylic acetates into the
corresponding 1, 3-dienes catalyzed by palladium in the presence of a base was …

Abstract Stereochemistry of the 1, 4-eliminative ring opening of [3-substituted (E)-1-propenyl]
oxiranes to the corresponding 2, 4-dienyl alcohols by LDA was investigated. The Z/E ratios …

Free‐radical carbo‐alkenylation of N‐aryl‐, N‐benzyl‐, and N‐phenethyl‐ene‐carbamates
with a disulfone provides vinyl sulfones which may then be functionalized and engaged in …