Copper–oxygen complexes revisited: structures, spectroscopy, and reactivity

CE Elwell, NL Gagnon, BD Neisen, D Dhar… - Chemical …, 2017 - ACS Publications
A longstanding research goal has been to understand the nature and role of copper–oxygen
intermediates within copper-containing enzymes and abiological catalysts. Synthetic …

Probing the binding and activation of small molecules by gas-phase transition metal clusters via IR spectroscopy

A Fielicke - Chemical Society Reviews, 2023 - pubs.rsc.org
Isolated transition metal clusters have been established as useful models for extended metal
surfaces or deposited metal particles, to improve the understanding of their surface …

Dynamic Behavior of Single-Atom Catalysts in Electrocatalysis: Identification of Cu-N3 as an Active Site for the Oxygen Reduction Reaction

J Yang, W Liu, M Xu, X Liu, H Qi, L Zhang… - Journal of the …, 2021 - ACS Publications
Atomically dispersed MNC (M refers to transition metals) materials represent the most
promising catalyst alternatives to the precious metal Pt for the electrochemical reduction of …

Metal–oxygen decoordination stabilizes anion redox in Li-rich oxides

J Hong, WE Gent, P **ao, K Lim, DH Seo, J Wu… - Nature materials, 2019 - nature.com
Reversible high-voltage redox chemistry is an essential component of many electrochemical
technologies, from (electro) catalysts to lithium-ion batteries. Oxygen-anion redox has …

Coupling structural evolution and oxygen-redox electrochemistry in layered transition metal oxides

D Eum, B Kim, JH Song, H Park, HY Jang, SJ Kim… - Nature Materials, 2022 - nature.com
Lattice oxygen redox offers an unexplored way to access superior electrochemical
properties of transition metal oxides (TMOs) for rechargeable batteries. However, the …

Synthetic Fe/Cu complexes: toward understanding heme-copper oxidase structure and function

SM Adam, GB Wijeratne, PJ Rogler, DE Diaz… - Chemical …, 2018 - ACS Publications
Heme-copper oxidases (HCOs) are terminal enzymes on the mitochondrial or bacterial
respiratory electron transport chain, which utilize a unique heterobinuclear active site to …

Structure and spectroscopy of copper− dioxygen complexes

LM Mirica, X Ottenwaelder, TDP Stack - Chemical Reviews, 2004 - ACS Publications
The reactions of Cu (I) complexes with O2 and the oxidative properties of the resulting
Cu/O2 complexes have attracted much interest during the past decades because of their …

Synthetic mononuclear nonheme iron–oxygen intermediates

W Nam - Accounts of chemical research, 2015 - ACS Publications
Conspectus Mononuclear nonheme iron–oxygen species, such as iron–superoxo,−
peroxo,− hydroperoxo, and− oxo, are key intermediates involved in dioxygen activation and …

Investigation of oxygen passivation for high-performance all-inorganic perovskite solar cells

SC Liu, Z Li, Y Yang, X Wang, YX Chen… - Journal of the …, 2019 - ACS Publications
Defect passivation using oxygen has been identified as an efficient and convenient
approach to suppress nonradiative recombination and improve the photovoltaic …

Oxidation catalysis over solid-state Keggin-type phosphomolybdic acid with oxygen defects

S Ishikawa, T Ikeda, M Koutani… - Journal of the …, 2022 - ACS Publications
Keggin-type phosphomolybdic acid (PMo12O40), treated with pyridine (Py), forms a
crystalline material (PyPMo-HT) following heat treatment under an inert gas flow at∼ 420° …